Effect of nanofibril cellulose empty fruit bunch-reinforced thermoplastic polyurethane nanocomposites on tensile and dynamic mechanical properties for flexible substrates

Researchers and scientists have focused on the development and future opportunities of flexible sensors in food, environment and defense fields. In this study, we propose a flexible substrate material-based nanofibril cellulose empty fruit bunch (NEFB)-reinforced thermoplastic polyurethane (TPU) ble...

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Main Authors: Azzra N.A., Atiqah A., Fadhlina H., Jalar A., Bakar M.A., Ismail A.G., Supian A.B.M.
Other Authors: 58785621300
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Published: John Wiley and Sons Inc 2025
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author Azzra N.A.
Atiqah A.
Fadhlina H.
Jalar A.
Bakar M.A.
Ismail A.G.
Supian A.B.M.
author2 58785621300
author_facet 58785621300
Azzra N.A.
Atiqah A.
Fadhlina H.
Jalar A.
Bakar M.A.
Ismail A.G.
Supian A.B.M.
author_sort Azzra N.A.
building UNITEN Library
collection Institutional Repository
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
continent Asia
country Malaysia
description Researchers and scientists have focused on the development and future opportunities of flexible sensors in food, environment and defense fields. In this study, we propose a flexible substrate material-based nanofibril cellulose empty fruit bunch (NEFB)-reinforced thermoplastic polyurethane (TPU) blend nanocomposite for flexible substrate materials. Untreated and treated nanofibril cellulose samples of empty fruit bunch (NEFB, 0, 1, 2, 3, 4 wt. %) were treated with 6 wt.% sodium hydroxide (NaOH) and subjected to internal Brabender mixer followed by a hot-pressing machine. The density and tensile and dynamic mechanical properties of the nanocomposites were investigated for the treated and untreated samples. Tensile properties were characterized using a Universal Testing Machine, and the fracture mechanism after post-tensile testing was determined by scanning electron microscopy (SEM). Increasing the content of untreated NEFB/TPU improved the tensile strength compared with 6% treated NEFB/TPU blend nanocomposites. Incorporating the nanofibril cellulose of empty fruit bunch at 2% into the TPU blend nanocomposites significantly increased E?, E" and Tg compared with other formulations. Highlights: Nanocellulose derived from plants is considered a promising material for flexible substrates in electronics due to its robust mechanical properties and eco-friendliness. Malaysia's abundant empty fruit bunch (EFB) resources make it a possible source of nanocellulose, which improves the properties of polymers. The effect of sodium hydroxide (NaOH) treatment on the compatibility of EFB-derived nanocellulose with polymer matrices was investigated. The addition of nanocellulose, particularly at a concentration of 1%, significantly increases the tensile strength of thermoplastic polyurethane nanocomposites, whereas 6% NaOH treatment has no effect. Dynamic mechanical analysis reveals high storage modulus at 2% nanofibril cellulose empty fruit bunch (NEFB) and energy dissipation at 4% NEFB as well as enhanced interfacial bonding at 1% NEFB. ? 2024 Society of Plastics Engineers.
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spelling my.uniten.dspace-362322025-03-03T15:41:38Z Effect of nanofibril cellulose empty fruit bunch-reinforced thermoplastic polyurethane nanocomposites on tensile and dynamic mechanical properties for flexible substrates Azzra N.A. Atiqah A. Fadhlina H. Jalar A. Bakar M.A. Ismail A.G. Supian A.B.M. 58785621300 55366998300 57980228500 11539926200 6701558715 36672954400 57202962691 Dynamics Fruits Hot Pressing Polyurethanes Scanning Electron Microscopy Sodium Hydroxide Density (specific gravity) Ductile fracture Dynamic mechanical analysis Dynamics Energy dissipation Flexible electronics Fracture testing Fruits Hot pressing Materials testing apparatus Nanocellulose Nanocomposites Nanofibers Polyurethanes Reinforced plastics Scanning electron microscopy Sodium hydroxide Substrates Tensile strength Biomedical devices Blend nanocomposites Empty fruit bunches Flexible substrate Nano-cellulose Nano-fibrils Nanofibril cellulose empty fruit bunch Plastic encapsulation Thermoplastic polyurethane nanocomposites Thermoplastic polyurethanes Tensile testing Researchers and scientists have focused on the development and future opportunities of flexible sensors in food, environment and defense fields. In this study, we propose a flexible substrate material-based nanofibril cellulose empty fruit bunch (NEFB)-reinforced thermoplastic polyurethane (TPU) blend nanocomposite for flexible substrate materials. Untreated and treated nanofibril cellulose samples of empty fruit bunch (NEFB, 0, 1, 2, 3, 4 wt. %) were treated with 6 wt.% sodium hydroxide (NaOH) and subjected to internal Brabender mixer followed by a hot-pressing machine. The density and tensile and dynamic mechanical properties of the nanocomposites were investigated for the treated and untreated samples. Tensile properties were characterized using a Universal Testing Machine, and the fracture mechanism after post-tensile testing was determined by scanning electron microscopy (SEM). Increasing the content of untreated NEFB/TPU improved the tensile strength compared with 6% treated NEFB/TPU blend nanocomposites. Incorporating the nanofibril cellulose of empty fruit bunch at 2% into the TPU blend nanocomposites significantly increased E?, E" and Tg compared with other formulations. Highlights: Nanocellulose derived from plants is considered a promising material for flexible substrates in electronics due to its robust mechanical properties and eco-friendliness. Malaysia's abundant empty fruit bunch (EFB) resources make it a possible source of nanocellulose, which improves the properties of polymers. The effect of sodium hydroxide (NaOH) treatment on the compatibility of EFB-derived nanocellulose with polymer matrices was investigated. The addition of nanocellulose, particularly at a concentration of 1%, significantly increases the tensile strength of thermoplastic polyurethane nanocomposites, whereas 6% NaOH treatment has no effect. Dynamic mechanical analysis reveals high storage modulus at 2% nanofibril cellulose empty fruit bunch (NEFB) and energy dissipation at 4% NEFB as well as enhanced interfacial bonding at 1% NEFB. ? 2024 Society of Plastics Engineers. Final 2025-03-03T07:41:38Z 2025-03-03T07:41:38Z 2024 Article 10.1002/pc.28788 2-s2.0-85199099191 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85199099191&doi=10.1002%2fpc.28788&partnerID=40&md5=4928fbcb0937bcf1591441ee76b89995 https://irepository.uniten.edu.my/handle/123456789/36232 45 16 14633 14643 John Wiley and Sons Inc Scopus
spellingShingle Dynamics
Fruits
Hot Pressing
Polyurethanes
Scanning Electron Microscopy
Sodium Hydroxide
Density (specific gravity)
Ductile fracture
Dynamic mechanical analysis
Dynamics
Energy dissipation
Flexible electronics
Fracture testing
Fruits
Hot pressing
Materials testing apparatus
Nanocellulose
Nanocomposites
Nanofibers
Polyurethanes
Reinforced plastics
Scanning electron microscopy
Sodium hydroxide
Substrates
Tensile strength
Biomedical devices
Blend nanocomposites
Empty fruit bunches
Flexible substrate
Nano-cellulose
Nano-fibrils
Nanofibril cellulose empty fruit bunch
Plastic encapsulation
Thermoplastic polyurethane nanocomposites
Thermoplastic polyurethanes
Tensile testing
Azzra N.A.
Atiqah A.
Fadhlina H.
Jalar A.
Bakar M.A.
Ismail A.G.
Supian A.B.M.
Effect of nanofibril cellulose empty fruit bunch-reinforced thermoplastic polyurethane nanocomposites on tensile and dynamic mechanical properties for flexible substrates
title Effect of nanofibril cellulose empty fruit bunch-reinforced thermoplastic polyurethane nanocomposites on tensile and dynamic mechanical properties for flexible substrates
title_full Effect of nanofibril cellulose empty fruit bunch-reinforced thermoplastic polyurethane nanocomposites on tensile and dynamic mechanical properties for flexible substrates
title_fullStr Effect of nanofibril cellulose empty fruit bunch-reinforced thermoplastic polyurethane nanocomposites on tensile and dynamic mechanical properties for flexible substrates
title_full_unstemmed Effect of nanofibril cellulose empty fruit bunch-reinforced thermoplastic polyurethane nanocomposites on tensile and dynamic mechanical properties for flexible substrates
title_short Effect of nanofibril cellulose empty fruit bunch-reinforced thermoplastic polyurethane nanocomposites on tensile and dynamic mechanical properties for flexible substrates
title_sort effect of nanofibril cellulose empty fruit bunch-reinforced thermoplastic polyurethane nanocomposites on tensile and dynamic mechanical properties for flexible substrates
topic Dynamics
Fruits
Hot Pressing
Polyurethanes
Scanning Electron Microscopy
Sodium Hydroxide
Density (specific gravity)
Ductile fracture
Dynamic mechanical analysis
Dynamics
Energy dissipation
Flexible electronics
Fracture testing
Fruits
Hot pressing
Materials testing apparatus
Nanocellulose
Nanocomposites
Nanofibers
Polyurethanes
Reinforced plastics
Scanning electron microscopy
Sodium hydroxide
Substrates
Tensile strength
Biomedical devices
Blend nanocomposites
Empty fruit bunches
Flexible substrate
Nano-cellulose
Nano-fibrils
Nanofibril cellulose empty fruit bunch
Plastic encapsulation
Thermoplastic polyurethane nanocomposites
Thermoplastic polyurethanes
Tensile testing
url_provider http://dspace.uniten.edu.my/