Hydrothermal synthesis of rGO and MnCoS composite for enhanced supercapacitor application

Nanostructured materials incorporating transition metal sulfides have demonstrated considerable potential across various applications, particularly in the realms of energy production and storage. Sulfide-based material preparation is a challenging and costly procedure that requires a high temperatur...

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Main Authors: Manikandan M., Prasankumar T., Manikandan E., Papanasam E., Ramesh K., Ramesh S.
Other Authors: 57219446093
Format: Article
Published: Nature Research 2025
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author Manikandan M.
Prasankumar T.
Manikandan E.
Papanasam E.
Ramesh K.
Ramesh S.
author2 57219446093
author_facet 57219446093
Manikandan M.
Prasankumar T.
Manikandan E.
Papanasam E.
Ramesh K.
Ramesh S.
author_sort Manikandan M.
building UNITEN Library
collection Institutional Repository
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
continent Asia
country Malaysia
description Nanostructured materials incorporating transition metal sulfides have demonstrated considerable potential across various applications, particularly in the realms of energy production and storage. Sulfide-based material preparation is a challenging and costly procedure that requires a high temperature and reducing atmosphere. This work reports that manganese cobalt sulfide (MCS) and reduced graphene oxide composite manganese cobalt sulfide (rMCS) were successfully prepared through a hydrothermal method. Various characterization techniques were employed to analyze the prepared materials, including X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, Brunauer-Emmett-Teller analysis, and X-ray photoelectron spectroscopy. In a three-electrode system, MCS and rMCS electrodes exhibit an excellent specific capacitance of 1695 and 1925�F g?1 at 1�A g?1 current density respectively. MCS delivers the capacitance retention of 99% and rMCS exhibits the capacitance retention of 100% capacitance retention over 5000 consecutive cycles. The constructed asymmetric supercapacitor electrode (rMCS//rGO) exhibits the energy and power density of 64 Wh kg?1 at 799�W kg?1, respectively with outstanding cyclic stability of 97.4% even after 10,000 cycles. The exceptional electrochemical properties of MCS with rGO composite electrode indicate that they would make an outstanding electrode material for cutting-edge energy storage devices. ? The Author(s) 2024.
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spelling my.uniten.dspace-360802025-03-03T15:41:21Z Hydrothermal synthesis of rGO and MnCoS composite for enhanced supercapacitor application Manikandan M. Prasankumar T. Manikandan E. Papanasam E. Ramesh K. Ramesh S. 57219446093 57191483300 57199646510 56565642400 57220754709 7103211834 cobalt graphene oxide manganese nanomaterial sulfide transition element article Brunauer Emmett Teller method controlled study current density density electrode energy yield field emission scanning electron microscopy high temperature synthesis three electrode system transmission electron microscopy X ray diffraction X ray photoemission spectroscopy Nanostructured materials incorporating transition metal sulfides have demonstrated considerable potential across various applications, particularly in the realms of energy production and storage. Sulfide-based material preparation is a challenging and costly procedure that requires a high temperature and reducing atmosphere. This work reports that manganese cobalt sulfide (MCS) and reduced graphene oxide composite manganese cobalt sulfide (rMCS) were successfully prepared through a hydrothermal method. Various characterization techniques were employed to analyze the prepared materials, including X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, Brunauer-Emmett-Teller analysis, and X-ray photoelectron spectroscopy. In a three-electrode system, MCS and rMCS electrodes exhibit an excellent specific capacitance of 1695 and 1925�F g?1 at 1�A g?1 current density respectively. MCS delivers the capacitance retention of 99% and rMCS exhibits the capacitance retention of 100% capacitance retention over 5000 consecutive cycles. The constructed asymmetric supercapacitor electrode (rMCS//rGO) exhibits the energy and power density of 64 Wh kg?1 at 799�W kg?1, respectively with outstanding cyclic stability of 97.4% even after 10,000 cycles. The exceptional electrochemical properties of MCS with rGO composite electrode indicate that they would make an outstanding electrode material for cutting-edge energy storage devices. ? The Author(s) 2024. Final 2025-03-03T07:41:21Z 2025-03-03T07:41:21Z 2024 Article 10.1038/s41598-024-77245-5 2-s2.0-85208095870 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85208095870&doi=10.1038%2fs41598-024-77245-5&partnerID=40&md5=34d97de1b4a71017c2f8fbc8b01c0b66 https://irepository.uniten.edu.my/handle/123456789/36080 14 1 25596 Nature Research Scopus
spellingShingle cobalt
graphene oxide
manganese
nanomaterial
sulfide
transition element
article
Brunauer Emmett Teller method
controlled study
current density
density
electrode
energy yield
field emission scanning electron microscopy
high temperature
synthesis
three electrode system
transmission electron microscopy
X ray diffraction
X ray photoemission spectroscopy
Manikandan M.
Prasankumar T.
Manikandan E.
Papanasam E.
Ramesh K.
Ramesh S.
Hydrothermal synthesis of rGO and MnCoS composite for enhanced supercapacitor application
title Hydrothermal synthesis of rGO and MnCoS composite for enhanced supercapacitor application
title_full Hydrothermal synthesis of rGO and MnCoS composite for enhanced supercapacitor application
title_fullStr Hydrothermal synthesis of rGO and MnCoS composite for enhanced supercapacitor application
title_full_unstemmed Hydrothermal synthesis of rGO and MnCoS composite for enhanced supercapacitor application
title_short Hydrothermal synthesis of rGO and MnCoS composite for enhanced supercapacitor application
title_sort hydrothermal synthesis of rgo and mncos composite for enhanced supercapacitor application
topic cobalt
graphene oxide
manganese
nanomaterial
sulfide
transition element
article
Brunauer Emmett Teller method
controlled study
current density
density
electrode
energy yield
field emission scanning electron microscopy
high temperature
synthesis
three electrode system
transmission electron microscopy
X ray diffraction
X ray photoemission spectroscopy
url_provider http://dspace.uniten.edu.my/