Incorporation of green solvent for low thermal budget flower-like Copper(I) Iodide (?-CuI) for high-efficiency solar cell
High conductivity, density, and uniform Copper(I) Iodide (CuI) as Hole Transporting Layer (HTL) was prepared directly on an Indium-doped Tin Oxide (ITO) substrate. A new green solvent, namely Monoethanolamine (MEA) with no additional additives procedures was presented for the preparation, though the...
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2024
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| author | Aliyaselvam O.V. Arith F. Mustafa A.N. Chelvanathan P. Azam M.A. Amin N. |
| author2 | 57224919906 |
| author_facet | 57224919906 Aliyaselvam O.V. Arith F. Mustafa A.N. Chelvanathan P. Azam M.A. Amin N. |
| author_sort | Aliyaselvam O.V. |
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| content_provider | Universiti Tenaga Nasional |
| content_source | UNITEN Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | High conductivity, density, and uniform Copper(I) Iodide (CuI) as Hole Transporting Layer (HTL) was prepared directly on an Indium-doped Tin Oxide (ITO) substrate. A new green solvent, namely Monoethanolamine (MEA) with no additional additives procedures was presented for the preparation, though the fabricated CuI films produced a notable result of HTL for perovskite solar cell (PSC) applications. The growth of ?-CuI can be formed at the lower temperature of 350��C, thereby lowering the fabrication cost since a high temperature involved fabrication method incurs large costs. The optimized annealing temperature of 80��C has attained a pristine morphology structure with high conductivity of 28.38 S/cm. Besides, the SCAPS-1D simulation was used to construct an efficient CuI-based PSC using the experimental data collected of fabricated CuI films and attained a PCE of 21.37%, FF of 82.77%, J sc of 22.74�mA/cm2 and V oc of 1.14�V. Interestingly, this is the first report proposing the use of MEA as a CuI solvent, demonstrating the effective combination of solvent and annealing temperature can yield a desirable CuI structure. With that, HTL films can be prepared in simple, inexpensive, and rapid, thus reducing the cost of solar cell production. � 2023, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature. |
| format | Article |
| id | my.uniten.dspace-34151 |
| institution | Universiti Tenaga Nasional |
| publishDate | 2024 |
| publisher | Springer |
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| spelling | my.uniten.dspace-341512024-10-14T11:18:10Z Incorporation of green solvent for low thermal budget flower-like Copper(I) Iodide (?-CuI) for high-efficiency solar cell Aliyaselvam O.V. Arith F. Mustafa A.N. Chelvanathan P. Azam M.A. Amin N. 57224919906 55799799900 57225353344 35766323200 37113662800 7102424614 Additives Budget control Ethanolamines Fabrication Film preparation Morphology Perovskite Perovskite solar cells Solvents Tin oxides Annealing temperatures Greener solvents High conductivity High-efficiency solar cells Hole transporting layers Indium doped tin oxides Low thermal budget Monoethanolamine Oxide substrates Solar-cell applications Copper compounds High conductivity, density, and uniform Copper(I) Iodide (CuI) as Hole Transporting Layer (HTL) was prepared directly on an Indium-doped Tin Oxide (ITO) substrate. A new green solvent, namely Monoethanolamine (MEA) with no additional additives procedures was presented for the preparation, though the fabricated CuI films produced a notable result of HTL for perovskite solar cell (PSC) applications. The growth of ?-CuI can be formed at the lower temperature of 350��C, thereby lowering the fabrication cost since a high temperature involved fabrication method incurs large costs. The optimized annealing temperature of 80��C has attained a pristine morphology structure with high conductivity of 28.38 S/cm. Besides, the SCAPS-1D simulation was used to construct an efficient CuI-based PSC using the experimental data collected of fabricated CuI films and attained a PCE of 21.37%, FF of 82.77%, J sc of 22.74�mA/cm2 and V oc of 1.14�V. Interestingly, this is the first report proposing the use of MEA as a CuI solvent, demonstrating the effective combination of solvent and annealing temperature can yield a desirable CuI structure. With that, HTL films can be prepared in simple, inexpensive, and rapid, thus reducing the cost of solar cell production. � 2023, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature. Final 2024-10-14T03:18:10Z 2024-10-14T03:18:10Z 2023 Article 10.1007/s10854-023-10578-5 2-s2.0-85160939056 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85160939056&doi=10.1007%2fs10854-023-10578-5&partnerID=40&md5=bfc431329095666b7e7e216b5aaed05b https://irepository.uniten.edu.my/handle/123456789/34151 34 16 1274 Springer Scopus |
| spellingShingle | Additives Budget control Ethanolamines Fabrication Film preparation Morphology Perovskite Perovskite solar cells Solvents Tin oxides Annealing temperatures Greener solvents High conductivity High-efficiency solar cells Hole transporting layers Indium doped tin oxides Low thermal budget Monoethanolamine Oxide substrates Solar-cell applications Copper compounds Aliyaselvam O.V. Arith F. Mustafa A.N. Chelvanathan P. Azam M.A. Amin N. Incorporation of green solvent for low thermal budget flower-like Copper(I) Iodide (?-CuI) for high-efficiency solar cell |
| title | Incorporation of green solvent for low thermal budget flower-like Copper(I) Iodide (?-CuI) for high-efficiency solar cell |
| title_full | Incorporation of green solvent for low thermal budget flower-like Copper(I) Iodide (?-CuI) for high-efficiency solar cell |
| title_fullStr | Incorporation of green solvent for low thermal budget flower-like Copper(I) Iodide (?-CuI) for high-efficiency solar cell |
| title_full_unstemmed | Incorporation of green solvent for low thermal budget flower-like Copper(I) Iodide (?-CuI) for high-efficiency solar cell |
| title_short | Incorporation of green solvent for low thermal budget flower-like Copper(I) Iodide (?-CuI) for high-efficiency solar cell |
| title_sort | incorporation of green solvent for low thermal budget flower-like copper(i) iodide (?-cui) for high-efficiency solar cell |
| topic | Additives Budget control Ethanolamines Fabrication Film preparation Morphology Perovskite Perovskite solar cells Solvents Tin oxides Annealing temperatures Greener solvents High conductivity High-efficiency solar cells Hole transporting layers Indium doped tin oxides Low thermal budget Monoethanolamine Oxide substrates Solar-cell applications Copper compounds |
| url_provider | http://dspace.uniten.edu.my/ |