Preparation, physico-chemical and spectroscopic investigation of thiacetazone and quinalizarin complexes with Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II)
Some new complexes of thiacetazone (Thz) and quinalizarin (Qz) with Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) were prepared. The ligands and their metal complexes were characterized by phisco-chemical spectroscopic techniques. The spectral data suggested that the thiacetazone...
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2023
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| author | Shaker S.A. Mohammed H.A. Salih A.A. |
| author2 | 31767661500 |
| author_facet | 31767661500 Shaker S.A. Mohammed H.A. Salih A.A. |
| author_sort | Shaker S.A. |
| building | UNITEN Library |
| collection | Institutional Repository |
| content_provider | Universiti Tenaga Nasional |
| content_source | UNITEN Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | Some new complexes of thiacetazone (Thz) and quinalizarin (Qz) with Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) were prepared. The ligands and their metal complexes were characterized by phisco-chemical spectroscopic techniques. The spectral data suggested that the thiacetazone as a neutral bidentate ligand is coordinated with the metal ions through the N and S atoms. The quinalizarin is negatively charged as a bidentate ligand and it is coordinated with the metal ions through the two O atoms. It is concluded that all the complexes of divalent metal ions have tetrahedral geometry except Pb(II) complex which has irregular tetrahedral geometry. � 2010, INSInet Publication. |
| format | Article |
| id | my.uniten.dspace-30649 |
| institution | Universiti Tenaga Nasional |
| publishDate | 2023 |
| record_format | dspace |
| spelling | my.uniten.dspace-306492023-12-29T15:50:49Z Preparation, physico-chemical and spectroscopic investigation of thiacetazone and quinalizarin complexes with Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) Shaker S.A. Mohammed H.A. Salih A.A. 31767661500 15837504600 37662158600 4-formylacetanilidethiosemicarbazone complexes Mixed ligand complexes Quinalizarin complexes Spectral studies Thiacetazone complexes Some new complexes of thiacetazone (Thz) and quinalizarin (Qz) with Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) were prepared. The ligands and their metal complexes were characterized by phisco-chemical spectroscopic techniques. The spectral data suggested that the thiacetazone as a neutral bidentate ligand is coordinated with the metal ions through the N and S atoms. The quinalizarin is negatively charged as a bidentate ligand and it is coordinated with the metal ions through the two O atoms. It is concluded that all the complexes of divalent metal ions have tetrahedral geometry except Pb(II) complex which has irregular tetrahedral geometry. � 2010, INSInet Publication. Final 2023-12-29T07:50:49Z 2023-12-29T07:50:49Z 2010 Article 2-s2.0-79956151022 https://www.scopus.com/inward/record.uri?eid=2-s2.0-79956151022&partnerID=40&md5=6d0df407d00866d600bc1aa73ba31a32 https://irepository.uniten.edu.my/handle/123456789/30649 4 10 5178 5183 Scopus |
| spellingShingle | 4-formylacetanilidethiosemicarbazone complexes Mixed ligand complexes Quinalizarin complexes Spectral studies Thiacetazone complexes Shaker S.A. Mohammed H.A. Salih A.A. Preparation, physico-chemical and spectroscopic investigation of thiacetazone and quinalizarin complexes with Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) |
| title | Preparation, physico-chemical and spectroscopic investigation of thiacetazone and quinalizarin complexes with Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) |
| title_full | Preparation, physico-chemical and spectroscopic investigation of thiacetazone and quinalizarin complexes with Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) |
| title_fullStr | Preparation, physico-chemical and spectroscopic investigation of thiacetazone and quinalizarin complexes with Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) |
| title_full_unstemmed | Preparation, physico-chemical and spectroscopic investigation of thiacetazone and quinalizarin complexes with Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) |
| title_short | Preparation, physico-chemical and spectroscopic investigation of thiacetazone and quinalizarin complexes with Mn(II), Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) |
| title_sort | preparation, physico-chemical and spectroscopic investigation of thiacetazone and quinalizarin complexes with mn(ii), fe(ii), co(ii), ni(ii), cu(ii), zn(ii), cd(ii) and pb(ii) |
| topic | 4-formylacetanilidethiosemicarbazone complexes Mixed ligand complexes Quinalizarin complexes Spectral studies Thiacetazone complexes |
| url_provider | http://dspace.uniten.edu.my/ |