Preparation, spectroscopic characterization of a new Cd(II) complex containing tridentate NNO Schiff base derived and X-ray crystallographic structural study of 3,4,5-trihydroxybenzoic acid[1-(pyridyl)-ethylidene] hydrazone
A new Cd(II) complex with a tridentate Schiff base derivative which was obtained from condensation of gallic hydrazid with 2-acetylpyridine has been prepared. The structure of the ligand 3,4,5-Trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone (GAPy) was confirmed using the X-ray structure anal...
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Sociedad Chilena de Quimica
2023
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| author | Alhadi A.A. Shaker S.A. Suleiman N.G. Yehye W.A. Ali H.M. |
| author2 | 24528394000 |
| author_facet | 24528394000 Alhadi A.A. Shaker S.A. Suleiman N.G. Yehye W.A. Ali H.M. |
| author_sort | Alhadi A.A. |
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| content_provider | Universiti Tenaga Nasional |
| content_source | UNITEN Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | A new Cd(II) complex with a tridentate Schiff base derivative which was obtained from condensation of gallic hydrazid with 2-acetylpyridine has been prepared. The structure of the ligand 3,4,5-Trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone (GAPy) was confirmed using the X-ray structure analysis. The elemental analysis, FTIR, UV-Vis, 1H NMR spectral and Thermal analysis indicates that the Schiff base ligand GAPy is a tridentate ligand which is coordinated with the Cd(II) complex through N,N and O atoms. Thus, the acetate ion is a bidentate ligand that is coordinated with the metal ion through two O atoms. |
| format | Article |
| id | my.uniten.dspace-30385 |
| institution | Universiti Tenaga Nasional |
| publishDate | 2023 |
| publisher | Sociedad Chilena de Quimica |
| record_format | dspace |
| spelling | my.uniten.dspace-303852023-12-29T15:47:16Z Preparation, spectroscopic characterization of a new Cd(II) complex containing tridentate NNO Schiff base derived and X-ray crystallographic structural study of 3,4,5-trihydroxybenzoic acid[1-(pyridyl)-ethylidene] hydrazone Alhadi A.A. Shaker S.A. Suleiman N.G. Yehye W.A. Ali H.M. 24528394000 31767661500 55587238700 24529410600 8375376900 Cd(II) complexes Hydrazone derivatives complexes Schiff base derivatives Spectroscopic characterization A new Cd(II) complex with a tridentate Schiff base derivative which was obtained from condensation of gallic hydrazid with 2-acetylpyridine has been prepared. The structure of the ligand 3,4,5-Trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone (GAPy) was confirmed using the X-ray structure analysis. The elemental analysis, FTIR, UV-Vis, 1H NMR spectral and Thermal analysis indicates that the Schiff base ligand GAPy is a tridentate ligand which is coordinated with the Cd(II) complex through N,N and O atoms. Thus, the acetate ion is a bidentate ligand that is coordinated with the metal ion through two O atoms. Final 2023-12-29T07:47:16Z 2023-12-29T07:47:16Z 2012 Article 10.4067/S0717-97072012000300018 2-s2.0-84873677185 https://www.scopus.com/inward/record.uri?eid=2-s2.0-84873677185&doi=10.4067%2fS0717-97072012000300018&partnerID=40&md5=1959a7c5f4e6ac4829f706bb20d10b52 https://irepository.uniten.edu.my/handle/123456789/30385 57 3 1283 1286 All Open Access; Gold Open Access; Green Open Access Sociedad Chilena de Quimica Scopus |
| spellingShingle | Cd(II) complexes Hydrazone derivatives complexes Schiff base derivatives Spectroscopic characterization Alhadi A.A. Shaker S.A. Suleiman N.G. Yehye W.A. Ali H.M. Preparation, spectroscopic characterization of a new Cd(II) complex containing tridentate NNO Schiff base derived and X-ray crystallographic structural study of 3,4,5-trihydroxybenzoic acid[1-(pyridyl)-ethylidene] hydrazone |
| title | Preparation, spectroscopic characterization of a new Cd(II) complex containing tridentate NNO Schiff base derived and X-ray crystallographic structural study of 3,4,5-trihydroxybenzoic acid[1-(pyridyl)-ethylidene] hydrazone |
| title_full | Preparation, spectroscopic characterization of a new Cd(II) complex containing tridentate NNO Schiff base derived and X-ray crystallographic structural study of 3,4,5-trihydroxybenzoic acid[1-(pyridyl)-ethylidene] hydrazone |
| title_fullStr | Preparation, spectroscopic characterization of a new Cd(II) complex containing tridentate NNO Schiff base derived and X-ray crystallographic structural study of 3,4,5-trihydroxybenzoic acid[1-(pyridyl)-ethylidene] hydrazone |
| title_full_unstemmed | Preparation, spectroscopic characterization of a new Cd(II) complex containing tridentate NNO Schiff base derived and X-ray crystallographic structural study of 3,4,5-trihydroxybenzoic acid[1-(pyridyl)-ethylidene] hydrazone |
| title_short | Preparation, spectroscopic characterization of a new Cd(II) complex containing tridentate NNO Schiff base derived and X-ray crystallographic structural study of 3,4,5-trihydroxybenzoic acid[1-(pyridyl)-ethylidene] hydrazone |
| title_sort | preparation, spectroscopic characterization of a new cd(ii) complex containing tridentate nno schiff base derived and x-ray crystallographic structural study of 3,4,5-trihydroxybenzoic acid[1-(pyridyl)-ethylidene] hydrazone |
| topic | Cd(II) complexes Hydrazone derivatives complexes Schiff base derivatives Spectroscopic characterization |
| url_provider | http://dspace.uniten.edu.my/ |