Synthesis and characterizations of mof-5 materials by nonsurfactant templating method for ammonia storage
Metal-organic frameworks (MOF-5) with non-surfactant templating method were successfully synthesized with cubic and tetragonal structure at ca. 0.26-0.63 �m. The syntheses were conducted at ambient condition, i.e. room temperature and pressure. Three types of fatty alcohols with different chain leng...
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Microscopy Society of Malaysia
2023
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| author | Othman S.Z. Misran H. Aminuddin A.M. Salim M.A. Shah N.N.H. Razak N.A.A. |
| author2 | 55548997100 |
| author_facet | 55548997100 Othman S.Z. Misran H. Aminuddin A.M. Salim M.A. Shah N.N.H. Razak N.A.A. |
| author_sort | Othman S.Z. |
| building | UNITEN Library |
| collection | Institutional Repository |
| content_provider | Universiti Tenaga Nasional |
| content_source | UNITEN Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | Metal-organic frameworks (MOF-5) with non-surfactant templating method were successfully synthesized with cubic and tetragonal structure at ca. 0.26-0.63 �m. The syntheses were conducted at ambient condition, i.e. room temperature and pressure. Three types of fatty alcohols with different chain length were used namely octyl alcohol, decyl alcohol and dodecyl alcohol. The results suggested that fatty alcohol chain length affected the relative crystallinity, morphology and competitive ammonia adsorption properties of MOF-5. MOF-5 synthesized with longer carbon chain fatty alcohol i.e. dodecyl alcohol resulted in higher relative crystallinity and higher ammonia uptake up to c.a. 4.6%. However, exposure to ammonia partially destroyed the crystal structure. � 2019, Microscopy Society of Malaysia. All rights reserved. |
| format | Article |
| id | my.uniten.dspace-30080 |
| institution | Universiti Tenaga Nasional |
| publishDate | 2023 |
| publisher | Microscopy Society of Malaysia |
| record_format | dspace |
| spelling | my.uniten.dspace-300802023-12-29T15:44:22Z Synthesis and characterizations of mof-5 materials by nonsurfactant templating method for ammonia storage Othman S.Z. Misran H. Aminuddin A.M. Salim M.A. Shah N.N.H. Razak N.A.A. 55548997100 6506899840 36981327400 57197124320 7401823793 58047108000 Ammonia uptake Crystal structure Fatty alcohol Mof-5 Non-surfactant template Metal-organic frameworks (MOF-5) with non-surfactant templating method were successfully synthesized with cubic and tetragonal structure at ca. 0.26-0.63 �m. The syntheses were conducted at ambient condition, i.e. room temperature and pressure. Three types of fatty alcohols with different chain length were used namely octyl alcohol, decyl alcohol and dodecyl alcohol. The results suggested that fatty alcohol chain length affected the relative crystallinity, morphology and competitive ammonia adsorption properties of MOF-5. MOF-5 synthesized with longer carbon chain fatty alcohol i.e. dodecyl alcohol resulted in higher relative crystallinity and higher ammonia uptake up to c.a. 4.6%. However, exposure to ammonia partially destroyed the crystal structure. � 2019, Microscopy Society of Malaysia. All rights reserved. Final 2023-12-29T07:44:22Z 2023-12-29T07:44:22Z 2013 Article 2-s2.0-85065160612 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85065160612&partnerID=40&md5=b04bdbd8bca889d1fc77e6ecff30a4ef https://irepository.uniten.edu.my/handle/123456789/30080 9 1 62 65 Microscopy Society of Malaysia Scopus |
| spellingShingle | Ammonia uptake Crystal structure Fatty alcohol Mof-5 Non-surfactant template Othman S.Z. Misran H. Aminuddin A.M. Salim M.A. Shah N.N.H. Razak N.A.A. Synthesis and characterizations of mof-5 materials by nonsurfactant templating method for ammonia storage |
| title | Synthesis and characterizations of mof-5 materials by nonsurfactant templating method for ammonia storage |
| title_full | Synthesis and characterizations of mof-5 materials by nonsurfactant templating method for ammonia storage |
| title_fullStr | Synthesis and characterizations of mof-5 materials by nonsurfactant templating method for ammonia storage |
| title_full_unstemmed | Synthesis and characterizations of mof-5 materials by nonsurfactant templating method for ammonia storage |
| title_short | Synthesis and characterizations of mof-5 materials by nonsurfactant templating method for ammonia storage |
| title_sort | synthesis and characterizations of mof-5 materials by nonsurfactant templating method for ammonia storage |
| topic | Ammonia uptake Crystal structure Fatty alcohol Mof-5 Non-surfactant template |
| url_provider | http://dspace.uniten.edu.my/ |