(SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance

Dye-sensitized solar cells; Electron transport properties; Mechanical stability; Nickel; Open circuit voltage; Particle size; Polymer solar cells; Polymerization; Silica; Sol-gel process; Sol-gels; Solar cells; Solid electrolytes; Thin films; Brunauer Emmett Teller analysis; Field emission electron...

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Main Authors: Abdullah H., Zainudin M.K., Ahmad M., Mahalingam S., Manap A.
Other Authors: 26025061200
Format: Article
Published: Institute for Ionics 2023
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author Abdullah H.
Zainudin M.K.
Ahmad M.
Mahalingam S.
Manap A.
author2 26025061200
author_facet 26025061200
Abdullah H.
Zainudin M.K.
Ahmad M.
Mahalingam S.
Manap A.
author_sort Abdullah H.
building UNITEN Library
collection Institutional Repository
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
continent Asia
country Malaysia
description Dye-sensitized solar cells; Electron transport properties; Mechanical stability; Nickel; Open circuit voltage; Particle size; Polymer solar cells; Polymerization; Silica; Sol-gel process; Sol-gels; Solar cells; Solid electrolytes; Thin films; Brunauer Emmett Teller analysis; Field emission electron microscopy; Gel polymer electrolytes; Polyacrylonitrile (PAN); Polymer gel electrolytes; Power conversion efficiencies; Sol-gel polymerization; Tetra-ethyl-ortho-silicate; Polyelectrolytes
format Article
id my.uniten.dspace-24620
institution Universiti Tenaga Nasional
publishDate 2023
publisher Institute for Ionics
record_format dspace
spelling my.uniten.dspace-246202023-05-29T15:25:12Z (SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance Abdullah H. Zainudin M.K. Ahmad M. Mahalingam S. Manap A. 26025061200 57205657943 57194770216 55434075500 57200642155 Dye-sensitized solar cells; Electron transport properties; Mechanical stability; Nickel; Open circuit voltage; Particle size; Polymer solar cells; Polymerization; Silica; Sol-gel process; Sol-gels; Solar cells; Solid electrolytes; Thin films; Brunauer Emmett Teller analysis; Field emission electron microscopy; Gel polymer electrolytes; Polyacrylonitrile (PAN); Polymer gel electrolytes; Power conversion efficiencies; Sol-gel polymerization; Tetra-ethyl-ortho-silicate; Polyelectrolytes This work aims on the degradation performance of (SiO2)100-x-Nix (x = 2.5, 10.0) photoanodes incorporating with liquid and gel polymer electrolyte for dye-sensitized solar cell (DSSC). The silica doped with nickel and gel polymer electrolyte was prepared by sol-gel polymerization of tetraethyl orthosilicate and sol-gel polymerization of polyacrylonitrile (PAN), respectively. The utilization of PAN-based gel polymer electrolyte improved the value of open circuit voltage due to its high ionic conductivity and mechanical stability in DSSC. The (SiO2)90.0-Ni10.0-based DSSC utilizing PAN-based gel polymer electrolyte exhibited the highest power conversion efficiency of 2.96%. The field emission electron microscopy images show larger average particle size with greater porosity in the (SiO2)90.0-Ni10.0 thin film. Moreover, the Brunauer-Emmett-Teller analysis determines greater active surface area on (SiO2)90.0-Ni10.0 thin films that indicates more dye molecules may adsorb on the mesoporous photoanode to facilitate electron transport in the DSSC. � 2019, Springer-Verlag GmbH Germany, part of Springer Nature. Final 2023-05-29T07:25:12Z 2023-05-29T07:25:12Z 2019 Article 10.1007/s11581-019-02886-w 2-s2.0-85060970695 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85060970695&doi=10.1007%2fs11581-019-02886-w&partnerID=40&md5=9ffd8bd2803a680b8d384b32cd70eb64 https://irepository.uniten.edu.my/handle/123456789/24620 25 7 3387 3396 Institute for Ionics Scopus
spellingShingle Abdullah H.
Zainudin M.K.
Ahmad M.
Mahalingam S.
Manap A.
(SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance
title (SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance
title_full (SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance
title_fullStr (SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance
title_full_unstemmed (SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance
title_short (SiO2)100-x-Nix (x = 2.5, 10.0) Composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance
title_sort (sio2)100-x-nix (x = 2.5, 10.0) composite-based photoanode with polymer gel electrolyte for increased dye-sensitized solar cell performance
url_provider http://dspace.uniten.edu.my/