Carbonised Agro-Waste Adsorbents for Automotive Lubricating Oil Removal

The increasing generation of waste lubricating oil, driven by expanding industrial and automotive activity, poses a significant threat to aquatic ecosystems due to its persistence, hydrophobicity, and complex chemical composition. This study evaluates two abundant agro-waste residue...

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Main Authors: Nivethah, Sokalinggam, Hasnida, Harun, Nurdalila, Saji, Nor Hazren, Abdul Hamid, Nor Maizzaty, Abdullah, Inawati, Othman, Noor Hasyimah, Rosman
Format: Article
Language:en
Published: Penerbit UTHM 2025
Subjects:
Online Access:http://ir.unimas.my/id/eprint/51113/1/10.%2B24284%2B102-109%20%281%29.pdf
http://ir.unimas.my/id/eprint/51113/
https://publisher.uthm.edu.my/ojs/index.php/jaita/article/view/24284/7718
https://doi.org/10.30880/jaita.2025.06.02.010
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author Nivethah, Sokalinggam
Hasnida, Harun
Nurdalila, Saji
Nor Hazren, Abdul Hamid
Nor Maizzaty, Abdullah
Inawati, Othman
Noor Hasyimah, Rosman
author_facet Nivethah, Sokalinggam
Hasnida, Harun
Nurdalila, Saji
Nor Hazren, Abdul Hamid
Nor Maizzaty, Abdullah
Inawati, Othman
Noor Hasyimah, Rosman
author_sort Nivethah, Sokalinggam
building Centre for Academic Information Services (CAIS)
collection Institutional Repository
content_provider Universiti Malaysia Sarawak
content_source UNIMAS Institutional Repository
continent Asia
country Malaysia
description The increasing generation of waste lubricating oil, driven by expanding industrial and automotive activity, poses a significant threat to aquatic ecosystems due to its persistence, hydrophobicity, and complex chemical composition. This study evaluates two abundant agro-waste residues: rice husk (RH) and sugarcane bagasse (SB) as potential adsorbents for lubricating oil removal. Both biomasses were pre-treated with 1M NaOH to enhance surface porosity and hydrophobicity, followed by carbonisation at 550 °C. Three adsorbent formulations were prepared based on RH:SB weight ratios of 24:6, 15:15, and 6:24 g. Batch experiments were conducted at oil concentrations of 25, 30, and 35 v/v% and contact times of 10, 20, and 30 min using a fixed 30g adsorbent dosage of RH and SB. The response behaviour was further examined using ANOVA and contour-plot analysis under Response Surface Methodology to interpret factor interactions. Optimum values for RH-SB adsorbent are 15:15 g of adsorbent dosage, 25 v/v% of oil concentration and 30 min of contact time. These resulted in 100% removal efficiency under controlled batch conditions. FTIR analysis confirmed the presence of lignocellulosic structures supporting oil–adsorbent interactions. Overall, the findings demonstrate that carbonised RH and SB are viable, low-cost, and environmentally sustainable adsorbents and are strongly recommended for removing used lubricating oil.
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spelling my.unimas.ir-511132025-12-23T07:08:36Z http://ir.unimas.my/id/eprint/51113/ Carbonised Agro-Waste Adsorbents for Automotive Lubricating Oil Removal Nivethah, Sokalinggam Hasnida, Harun Nurdalila, Saji Nor Hazren, Abdul Hamid Nor Maizzaty, Abdullah Inawati, Othman Noor Hasyimah, Rosman TA Engineering (General). Civil engineering (General) The increasing generation of waste lubricating oil, driven by expanding industrial and automotive activity, poses a significant threat to aquatic ecosystems due to its persistence, hydrophobicity, and complex chemical composition. This study evaluates two abundant agro-waste residues: rice husk (RH) and sugarcane bagasse (SB) as potential adsorbents for lubricating oil removal. Both biomasses were pre-treated with 1M NaOH to enhance surface porosity and hydrophobicity, followed by carbonisation at 550 °C. Three adsorbent formulations were prepared based on RH:SB weight ratios of 24:6, 15:15, and 6:24 g. Batch experiments were conducted at oil concentrations of 25, 30, and 35 v/v% and contact times of 10, 20, and 30 min using a fixed 30g adsorbent dosage of RH and SB. The response behaviour was further examined using ANOVA and contour-plot analysis under Response Surface Methodology to interpret factor interactions. Optimum values for RH-SB adsorbent are 15:15 g of adsorbent dosage, 25 v/v% of oil concentration and 30 min of contact time. These resulted in 100% removal efficiency under controlled batch conditions. FTIR analysis confirmed the presence of lignocellulosic structures supporting oil–adsorbent interactions. Overall, the findings demonstrate that carbonised RH and SB are viable, low-cost, and environmentally sustainable adsorbents and are strongly recommended for removing used lubricating oil. Penerbit UTHM 2025-12-31 Article PeerReviewed text en http://ir.unimas.my/id/eprint/51113/1/10.%2B24284%2B102-109%20%281%29.pdf Nivethah, Sokalinggam and Hasnida, Harun and Nurdalila, Saji and Nor Hazren, Abdul Hamid and Nor Maizzaty, Abdullah and Inawati, Othman and Noor Hasyimah, Rosman (2025) Carbonised Agro-Waste Adsorbents for Automotive Lubricating Oil Removal. JOURNAL OF ADVANCED INDUSTRIAL TECHNOLOGY AND APPLICATION, 6 (2). pp. 102-109. ISSN 2716-7097 https://publisher.uthm.edu.my/ojs/index.php/jaita/article/view/24284/7718 https://doi.org/10.30880/jaita.2025.06.02.010
spellingShingle TA Engineering (General). Civil engineering (General)
Nivethah, Sokalinggam
Hasnida, Harun
Nurdalila, Saji
Nor Hazren, Abdul Hamid
Nor Maizzaty, Abdullah
Inawati, Othman
Noor Hasyimah, Rosman
Carbonised Agro-Waste Adsorbents for Automotive Lubricating Oil Removal
title Carbonised Agro-Waste Adsorbents for Automotive Lubricating Oil Removal
title_full Carbonised Agro-Waste Adsorbents for Automotive Lubricating Oil Removal
title_fullStr Carbonised Agro-Waste Adsorbents for Automotive Lubricating Oil Removal
title_full_unstemmed Carbonised Agro-Waste Adsorbents for Automotive Lubricating Oil Removal
title_short Carbonised Agro-Waste Adsorbents for Automotive Lubricating Oil Removal
title_sort carbonised agro-waste adsorbents for automotive lubricating oil removal
topic TA Engineering (General). Civil engineering (General)
url http://ir.unimas.my/id/eprint/51113/1/10.%2B24284%2B102-109%20%281%29.pdf
http://ir.unimas.my/id/eprint/51113/
https://publisher.uthm.edu.my/ojs/index.php/jaita/article/view/24284/7718
https://doi.org/10.30880/jaita.2025.06.02.010
url_provider http://ir.unimas.my/