Substituted Methoxybenzene derivatives: C8H9NO4, C9H11NO5 and C13H18O4

The structures of three methoxybenzenes, namely 1,2-dimethoxy-4-nitrobenzene, C8H9NO4, (I), 1,2,3-trimethoxy-5-nitrobenzene, C9H11NO5, (II), and 1-(2,4,5-trimethoxyphenyl)-1-butanone, C13H18O4, (III), are reported. Molecules of (I) and (III) are planar, but one of the three methoxy groups of (II) is...

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Bibliographic Details
Main Authors: Fun, H.-K., Chinnakali, K., Sivakumar, K., Sam, T.-W., How, Siew Eng
Format: Article
Language:en
Published: 1997
Subjects:
Online Access:https://eprints.ums.edu.my/id/eprint/18935/1/Substituted%20methoxybenzene%20derivatives.pdf
https://eprints.ums.edu.my/id/eprint/18935/
https://doi.org/10.1107/S010827019700975X
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Summary:The structures of three methoxybenzenes, namely 1,2-dimethoxy-4-nitrobenzene, C8H9NO4, (I), 1,2,3-trimethoxy-5-nitrobenzene, C9H11NO5, (II), and 1-(2,4,5-trimethoxyphenyl)-1-butanone, C13H18O4, (III), are reported. Molecules of (I) and (III) are planar, but one of the three methoxy groups of (II) is twisted out of the phenyl ring plane as a result of steric hindrance. In all three solids, the molecules are linked to form centrosymmetrically hydrogen-bonded dimers; they are packed in parallel layers in (I) and (II), but in zigzag layers in (III).