Facile Synthesis of Copper Nanoparticles in Glycerol at Room Temperature: Formation Mechanism
A copper sol is usually synthesized by the reduction of a copper precursor with a suitable reducing agent in the presence of a stabilizer. There are few reports regarding the preparation of copper nanoparticles in glycerol without using a stabilizing agent, but at elevated temperatures. The formatio...
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Royal Society of Chemistry
2015
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| Online Access: | http://umpir.ump.edu.my/id/eprint/9080/1/fkksa-2015-maksudur-Facile%20Synthesis%20of%20Copper.pdf http://umpir.ump.edu.my/id/eprint/9080/7/fkksa-2015-maksudur-facile%20synthesis%20of%20copper%20nanoparticles-full.pdf http://umpir.ump.edu.my/id/eprint/9080/ http://dx.doi.org/10.1039/C4RA16919K |
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| author | Huei, Ruey Ong Khan, Maksudur R. Ridzuan, Ramli Yonghua, Du Shibo, Xi R. M., Yunus |
| author_facet | Huei, Ruey Ong Khan, Maksudur R. Ridzuan, Ramli Yonghua, Du Shibo, Xi R. M., Yunus |
| author_sort | Huei, Ruey Ong |
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| content_provider | Universiti Malaysia Pahang Al-Sultan Abdullah |
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| continent | Asia |
| country | Malaysia |
| description | A copper sol is usually synthesized by the reduction of a copper precursor with a suitable reducing agent in the presence of a stabilizer. There are few reports regarding the preparation of copper nanoparticles in glycerol without using a stabilizing agent, but at elevated temperatures. The formation of reduced copper (Cu0) is usually verified by a UV-vis spectrophotometer where a ‘red copper sol’ was formed. In the present paper we synthesized the copper sol at room temperature in a glycerol medium using hydrazine as a reducing agent. The chemical states of copper in the sol and their composition were analyzed by X-ray absorption near edge structure spectroscopy (XANES) with the linear composition fitting method. A series-parallel mechanism of the reaction was proposed. An average particle size of 5 ± 1 nm was visualized via transmission electron microscopy (TEM). |
| format | Article |
| id | my.ump.umpir.9080 |
| institution | Universiti Malaysia Pahang |
| language | en en |
| publishDate | 2015 |
| publisher | Royal Society of Chemistry |
| record_format | eprints |
| spelling | my.ump.umpir.90802018-01-15T04:17:29Z http://umpir.ump.edu.my/id/eprint/9080/ Facile Synthesis of Copper Nanoparticles in Glycerol at Room Temperature: Formation Mechanism Huei, Ruey Ong Khan, Maksudur R. Ridzuan, Ramli Yonghua, Du Shibo, Xi R. M., Yunus TP Chemical technology A copper sol is usually synthesized by the reduction of a copper precursor with a suitable reducing agent in the presence of a stabilizer. There are few reports regarding the preparation of copper nanoparticles in glycerol without using a stabilizing agent, but at elevated temperatures. The formation of reduced copper (Cu0) is usually verified by a UV-vis spectrophotometer where a ‘red copper sol’ was formed. In the present paper we synthesized the copper sol at room temperature in a glycerol medium using hydrazine as a reducing agent. The chemical states of copper in the sol and their composition were analyzed by X-ray absorption near edge structure spectroscopy (XANES) with the linear composition fitting method. A series-parallel mechanism of the reaction was proposed. An average particle size of 5 ± 1 nm was visualized via transmission electron microscopy (TEM). Royal Society of Chemistry 2015 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/9080/1/fkksa-2015-maksudur-Facile%20Synthesis%20of%20Copper.pdf application/pdf en http://umpir.ump.edu.my/id/eprint/9080/7/fkksa-2015-maksudur-facile%20synthesis%20of%20copper%20nanoparticles-full.pdf Huei, Ruey Ong and Khan, Maksudur R. and Ridzuan, Ramli and Yonghua, Du and Shibo, Xi and R. M., Yunus (2015) Facile Synthesis of Copper Nanoparticles in Glycerol at Room Temperature: Formation Mechanism. RSC Advances, 5 (31). pp. 24544-24549. ISSN 2046-2069. (Published) http://dx.doi.org/10.1039/C4RA16919K doi: 10.1039/C4RA16919K |
| spellingShingle | TP Chemical technology Huei, Ruey Ong Khan, Maksudur R. Ridzuan, Ramli Yonghua, Du Shibo, Xi R. M., Yunus Facile Synthesis of Copper Nanoparticles in Glycerol at Room Temperature: Formation Mechanism |
| title | Facile Synthesis of Copper Nanoparticles in Glycerol at Room Temperature: Formation Mechanism |
| title_full | Facile Synthesis of Copper Nanoparticles in Glycerol at Room Temperature: Formation Mechanism |
| title_fullStr | Facile Synthesis of Copper Nanoparticles in Glycerol at Room Temperature: Formation Mechanism |
| title_full_unstemmed | Facile Synthesis of Copper Nanoparticles in Glycerol at Room Temperature: Formation Mechanism |
| title_short | Facile Synthesis of Copper Nanoparticles in Glycerol at Room Temperature: Formation Mechanism |
| title_sort | facile synthesis of copper nanoparticles in glycerol at room temperature: formation mechanism |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/9080/1/fkksa-2015-maksudur-Facile%20Synthesis%20of%20Copper.pdf http://umpir.ump.edu.my/id/eprint/9080/7/fkksa-2015-maksudur-facile%20synthesis%20of%20copper%20nanoparticles-full.pdf http://umpir.ump.edu.my/id/eprint/9080/ http://dx.doi.org/10.1039/C4RA16919K |
| url_provider | http://umpir.ump.edu.my/ |