Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells

Working electrode (WE) fabrication offers significant challenges in terms of achieving high-efficiency dye-sensitized solar cells (DSCs). We have combined the beneficial effects of vertical nanorods grown on conducting glass substrate for charge transport and mesoporous particles for dye loading and...

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Main Authors: Irfan, Ahmed, Fakharuddin, Azhar, Qamar, Wali, Ayib Rosdi, Zainun, Jamil, Ismail, Rajan, Jose
Format: Article
Language:en
Published: IOP Publishing Ltd 2015
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/8604/1/fist-2015-rajan-Mesoporous%20Titania-Vertical-abs.pdf
http://umpir.ump.edu.my/id/eprint/8604/
http://dx.doi.org/10.1088/0957-4484/26/10/105401
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author Irfan, Ahmed
Fakharuddin, Azhar
Qamar, Wali
Ayib Rosdi, Zainun
Jamil, Ismail
Rajan, Jose
author_facet Irfan, Ahmed
Fakharuddin, Azhar
Qamar, Wali
Ayib Rosdi, Zainun
Jamil, Ismail
Rajan, Jose
author_sort Irfan, Ahmed
building UMPSA Library
collection Institutional Repository
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
continent Asia
country Malaysia
description Working electrode (WE) fabrication offers significant challenges in terms of achieving high-efficiency dye-sensitized solar cells (DSCs). We have combined the beneficial effects of vertical nanorods grown on conducting glass substrate for charge transport and mesoporous particles for dye loading and have achieved a high photoconversion efficiency of (η) > 11% with an internal quantum efficiency of ~93% in electrode films of thickness ~7 ± 0.5 μm. Controlling the interface between the vertical nanorods and the mesoporous film is a crucial step in attaining high η. We identify three parameters, viz., large surface area of nanoparticles, increased light scattering of the nanorod�nanoparticle layer, and superior charge transport of nanorods, that simultaneously contribute to the improved photovoltaic performance of the WE developed.
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id my.ump.umpir.8604
institution Universiti Malaysia Pahang
language en
publishDate 2015
publisher IOP Publishing Ltd
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spelling my.ump.umpir.86042018-02-08T03:13:51Z http://umpir.ump.edu.my/id/eprint/8604/ Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells Irfan, Ahmed Fakharuddin, Azhar Qamar, Wali Ayib Rosdi, Zainun Jamil, Ismail Rajan, Jose QC Physics QD Chemistry T Technology (General) TK Electrical engineering. Electronics Nuclear engineering Working electrode (WE) fabrication offers significant challenges in terms of achieving high-efficiency dye-sensitized solar cells (DSCs). We have combined the beneficial effects of vertical nanorods grown on conducting glass substrate for charge transport and mesoporous particles for dye loading and have achieved a high photoconversion efficiency of (η) > 11% with an internal quantum efficiency of ~93% in electrode films of thickness ~7 ± 0.5 μm. Controlling the interface between the vertical nanorods and the mesoporous film is a crucial step in attaining high η. We identify three parameters, viz., large surface area of nanoparticles, increased light scattering of the nanorod�nanoparticle layer, and superior charge transport of nanorods, that simultaneously contribute to the improved photovoltaic performance of the WE developed. IOP Publishing Ltd 2015-03-13 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/8604/1/fist-2015-rajan-Mesoporous%20Titania-Vertical-abs.pdf Irfan, Ahmed and Fakharuddin, Azhar and Qamar, Wali and Ayib Rosdi, Zainun and Jamil, Ismail and Rajan, Jose (2015) Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells. Nanotechnology, 26 (105401). pp. 1-8. ISSN 0957-4484. (Published) http://dx.doi.org/10.1088/0957-4484/26/10/105401 DOI: 10.1088/0957-4484/26/10/105401
spellingShingle QC Physics
QD Chemistry
T Technology (General)
TK Electrical engineering. Electronics Nuclear engineering
Irfan, Ahmed
Fakharuddin, Azhar
Qamar, Wali
Ayib Rosdi, Zainun
Jamil, Ismail
Rajan, Jose
Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells
title Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells
title_full Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells
title_fullStr Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells
title_full_unstemmed Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells
title_short Mesoporous Titania-Vertical Nanorod Films With Interfacial Engineering For High Performance Dye-Sensitized Solar Cells
title_sort mesoporous titania-vertical nanorod films with interfacial engineering for high performance dye-sensitized solar cells
topic QC Physics
QD Chemistry
T Technology (General)
TK Electrical engineering. Electronics Nuclear engineering
url http://umpir.ump.edu.my/id/eprint/8604/1/fist-2015-rajan-Mesoporous%20Titania-Vertical-abs.pdf
http://umpir.ump.edu.my/id/eprint/8604/
http://dx.doi.org/10.1088/0957-4484/26/10/105401
url_provider http://umpir.ump.edu.my/