Photodegradation of 2-chlorophenol over ZnO/KCC-1: Reaction optimization by response surface methodology
Removing 2-chlorophenol (2CP) from water is an imperative task due to its toxicity. Various methods have been introduced for 2CP removal, and photocatalytic degradation is one of the best alternative solutions due to its effectiveness and simple process. This study focused on the potency of ZnO/KCC-...
Saved in:
| Main Authors: | , , , |
|---|---|
| Format: | Conference or Workshop Item |
| Language: | en en en |
| Published: |
Elsevier Ltd
2023
|
| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/37193/1/Photodegradation%20of%202-chlorophenol%20over%20zno_kcc-1_%20reaction%20optimization%20by%20response%20surface%20methodology.pdf http://umpir.ump.edu.my/id/eprint/37193/7/Photodegradation%20of%202-chlorophenol%20over%20ZnO-KCC-1.pdf http://umpir.ump.edu.my/id/eprint/37193/8/Photodegradation%20of%202-chlorophenol%20over%20ZnO-KCC-1_FULL.pdf http://umpir.ump.edu.my/id/eprint/37193/ https://doi.org/10.1016/j.matpr.2023.02.309 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1831529285751406592 |
|---|---|
| author | Ros Shazuin Rayyanu, Mohd Zaki Lim, X. R. Herma Dina, Setiabudi Nur Fitriah, Mohd Jaafar |
| author_facet | Ros Shazuin Rayyanu, Mohd Zaki Lim, X. R. Herma Dina, Setiabudi Nur Fitriah, Mohd Jaafar |
| author_sort | Ros Shazuin Rayyanu, Mohd Zaki |
| building | UMPSA Library |
| collection | Institutional Repository |
| content_provider | Universiti Malaysia Pahang Al-Sultan Abdullah |
| content_source | UMPSA Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | Removing 2-chlorophenol (2CP) from water is an imperative task due to its toxicity. Various methods have been introduced for 2CP removal, and photocatalytic degradation is one of the best alternative solutions due to its effectiveness and simple process. This study focused on the potency of ZnO/KCC-1 as an effective photocatalyst for 2CP elimination from aqueous solutions. ZnO/KCC-1 was prepared by impregnation of commercial ZnO precursor into the synthesized KCC-1. The synthesized Zn/KCC-1 was characterized by using TEM, FESEM, XRD, FTIR, and PL. The characterization results revealed that the addition of ZnO did not cause the collapse of the dendrimeric structure of KCC-1. The analysis via response surface methodology (RSM) over independent variables of initial concentration (X1), catalyst dosage (X2), and pH (X3) revealed that X2 was the most essential variable, while X1 was the least significant variable. The ideal parameter for 2CP degradation was achieved at X1 = 10 mg/L, X2 = 2 g/L, and X3 = 10 with photodegradation efficiency (Y) of 90.62% (predicted) and 88.93% (experimental). This research revealed that ZnO/KCC-1 had a good potential for photocatalytic degradation of 2CP from an aqueous solution. |
| format | Conference or Workshop Item |
| id | my.ump.umpir.37193 |
| institution | Universiti Malaysia Pahang |
| language | en en en |
| publishDate | 2023 |
| publisher | Elsevier Ltd |
| record_format | eprints |
| spelling | my.ump.umpir.371932024-06-13T04:28:21Z http://umpir.ump.edu.my/id/eprint/37193/ Photodegradation of 2-chlorophenol over ZnO/KCC-1: Reaction optimization by response surface methodology Ros Shazuin Rayyanu, Mohd Zaki Lim, X. R. Herma Dina, Setiabudi Nur Fitriah, Mohd Jaafar QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology Removing 2-chlorophenol (2CP) from water is an imperative task due to its toxicity. Various methods have been introduced for 2CP removal, and photocatalytic degradation is one of the best alternative solutions due to its effectiveness and simple process. This study focused on the potency of ZnO/KCC-1 as an effective photocatalyst for 2CP elimination from aqueous solutions. ZnO/KCC-1 was prepared by impregnation of commercial ZnO precursor into the synthesized KCC-1. The synthesized Zn/KCC-1 was characterized by using TEM, FESEM, XRD, FTIR, and PL. The characterization results revealed that the addition of ZnO did not cause the collapse of the dendrimeric structure of KCC-1. The analysis via response surface methodology (RSM) over independent variables of initial concentration (X1), catalyst dosage (X2), and pH (X3) revealed that X2 was the most essential variable, while X1 was the least significant variable. The ideal parameter for 2CP degradation was achieved at X1 = 10 mg/L, X2 = 2 g/L, and X3 = 10 with photodegradation efficiency (Y) of 90.62% (predicted) and 88.93% (experimental). This research revealed that ZnO/KCC-1 had a good potential for photocatalytic degradation of 2CP from an aqueous solution. Elsevier Ltd 2023-03-07 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/37193/1/Photodegradation%20of%202-chlorophenol%20over%20zno_kcc-1_%20reaction%20optimization%20by%20response%20surface%20methodology.pdf pdf en http://umpir.ump.edu.my/id/eprint/37193/7/Photodegradation%20of%202-chlorophenol%20over%20ZnO-KCC-1.pdf pdf en http://umpir.ump.edu.my/id/eprint/37193/8/Photodegradation%20of%202-chlorophenol%20over%20ZnO-KCC-1_FULL.pdf Ros Shazuin Rayyanu, Mohd Zaki and Lim, X. R. and Herma Dina, Setiabudi and Nur Fitriah, Mohd Jaafar (2023) Photodegradation of 2-chlorophenol over ZnO/KCC-1: Reaction optimization by response surface methodology. In: Materials Today: Proceedings. Materials Today: Proceedings; 6th National Conference for Postgraduate Research (NCON-PGR 2022) , 15 November 2022 , Virtual, Online. pp. 1-7.. ISSN 2214-7853 (In Press / Online First) (In Press / Online First) https://doi.org/10.1016/j.matpr.2023.02.309 |
| spellingShingle | QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology Ros Shazuin Rayyanu, Mohd Zaki Lim, X. R. Herma Dina, Setiabudi Nur Fitriah, Mohd Jaafar Photodegradation of 2-chlorophenol over ZnO/KCC-1: Reaction optimization by response surface methodology |
| title | Photodegradation of 2-chlorophenol over ZnO/KCC-1: Reaction optimization by response surface methodology |
| title_full | Photodegradation of 2-chlorophenol over ZnO/KCC-1: Reaction optimization by response surface methodology |
| title_fullStr | Photodegradation of 2-chlorophenol over ZnO/KCC-1: Reaction optimization by response surface methodology |
| title_full_unstemmed | Photodegradation of 2-chlorophenol over ZnO/KCC-1: Reaction optimization by response surface methodology |
| title_short | Photodegradation of 2-chlorophenol over ZnO/KCC-1: Reaction optimization by response surface methodology |
| title_sort | photodegradation of 2-chlorophenol over zno/kcc-1: reaction optimization by response surface methodology |
| topic | QD Chemistry T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/37193/1/Photodegradation%20of%202-chlorophenol%20over%20zno_kcc-1_%20reaction%20optimization%20by%20response%20surface%20methodology.pdf http://umpir.ump.edu.my/id/eprint/37193/7/Photodegradation%20of%202-chlorophenol%20over%20ZnO-KCC-1.pdf http://umpir.ump.edu.my/id/eprint/37193/8/Photodegradation%20of%202-chlorophenol%20over%20ZnO-KCC-1_FULL.pdf http://umpir.ump.edu.my/id/eprint/37193/ https://doi.org/10.1016/j.matpr.2023.02.309 |
| url_provider | http://umpir.ump.edu.my/ |