Catalytic upgrading of biomass-derived pyrolysis vapour over metal-modified HZSM-5 into BTX: a comprehensive review
This paper provides an updated and comprehensive review on the catalytic upgrading of biomass-derived pyrolysis vapours over metal-modified HZSM-5 catalyst into bio-aromatic hydrocarbons. The catalytic upgrading of biomass pyrolysis vapours seems to be a promising technology in generating gasoline-t...
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| Language: | en |
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2020
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| Online Access: | http://umpir.ump.edu.my/id/eprint/30209/1/Catalytic%20upgrading%20of%20biomass-derived%20pyrolysis%20vapour%20over%20metal.pdf http://umpir.ump.edu.my/id/eprint/30209/ https://doi.org/10.1007/s13399-020-00909-5 |
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| author | Balasundram, Vekes Norazana, Ibrahim Rafiziana, Md. Kasmani Ruzinah, Isha Mohd. Kamaruddin, Abd. Hamid Hasrinah, Hasbullah |
| author_facet | Balasundram, Vekes Norazana, Ibrahim Rafiziana, Md. Kasmani Ruzinah, Isha Mohd. Kamaruddin, Abd. Hamid Hasrinah, Hasbullah |
| author_sort | Balasundram, Vekes |
| building | UMPSA Library |
| collection | Institutional Repository |
| content_provider | Universiti Malaysia Pahang Al-Sultan Abdullah |
| content_source | UMPSA Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | This paper provides an updated and comprehensive review on the catalytic upgrading of biomass-derived pyrolysis vapours over metal-modified HZSM-5 catalyst into bio-aromatic hydrocarbons. The catalytic upgrading of biomass pyrolysis vapours seems to be a promising technology in generating gasoline-type bio-aromatic hydrocarbons, i.e. benzene, toluene and xylene (BTX). Biomass-derived raw pyrolysis oil has high oxygenated compounds that deteriorate pyrolysis oil properties and limits its applications. Metal modification of hydrogen exchanged Zeolite Socony Mobil Five (HZSM-5) catalyst has gained attention in a biomass pyrolysis research area due to the beneficial effects on upgrading the oxygenated pyrolysis vapours into BTX-enriched pyrolysis oils. The influence of metals (alkali and alkaline earth metals, transition metals and rare earth metals) as bi-functional or multifunctional activity on HZSM-5 catalyst during pyrolysis has been addressed. The effect of reaction temperature, the type of metals, metal contents, the silica-to-alumina ratio of catalyst and the catalyst-tobiomass ratio are critically discussed for maximum production of monocyclic aromatic hydrocarbons during the upgrading of pyrolysis vapours. Finally, concluding remarks on metal-modified zeolite catalyst and future recommendation in upgrading biomass pyrolysis vapours are presented. |
| format | Article |
| id | my.ump.umpir.30209 |
| institution | Universiti Malaysia Pahang |
| language | en |
| publishDate | 2020 |
| publisher | Springer |
| record_format | eprints |
| spelling | my.ump.umpir.302092022-04-27T02:34:19Z http://umpir.ump.edu.my/id/eprint/30209/ Catalytic upgrading of biomass-derived pyrolysis vapour over metal-modified HZSM-5 into BTX: a comprehensive review Balasundram, Vekes Norazana, Ibrahim Rafiziana, Md. Kasmani Ruzinah, Isha Mohd. Kamaruddin, Abd. Hamid Hasrinah, Hasbullah TP Chemical technology This paper provides an updated and comprehensive review on the catalytic upgrading of biomass-derived pyrolysis vapours over metal-modified HZSM-5 catalyst into bio-aromatic hydrocarbons. The catalytic upgrading of biomass pyrolysis vapours seems to be a promising technology in generating gasoline-type bio-aromatic hydrocarbons, i.e. benzene, toluene and xylene (BTX). Biomass-derived raw pyrolysis oil has high oxygenated compounds that deteriorate pyrolysis oil properties and limits its applications. Metal modification of hydrogen exchanged Zeolite Socony Mobil Five (HZSM-5) catalyst has gained attention in a biomass pyrolysis research area due to the beneficial effects on upgrading the oxygenated pyrolysis vapours into BTX-enriched pyrolysis oils. The influence of metals (alkali and alkaline earth metals, transition metals and rare earth metals) as bi-functional or multifunctional activity on HZSM-5 catalyst during pyrolysis has been addressed. The effect of reaction temperature, the type of metals, metal contents, the silica-to-alumina ratio of catalyst and the catalyst-tobiomass ratio are critically discussed for maximum production of monocyclic aromatic hydrocarbons during the upgrading of pyrolysis vapours. Finally, concluding remarks on metal-modified zeolite catalyst and future recommendation in upgrading biomass pyrolysis vapours are presented. Springer 2020-08-05 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/30209/1/Catalytic%20upgrading%20of%20biomass-derived%20pyrolysis%20vapour%20over%20metal.pdf Balasundram, Vekes and Norazana, Ibrahim and Rafiziana, Md. Kasmani and Ruzinah, Isha and Mohd. Kamaruddin, Abd. Hamid and Hasrinah, Hasbullah (2020) Catalytic upgrading of biomass-derived pyrolysis vapour over metal-modified HZSM-5 into BTX: a comprehensive review. Biomass Conversion and Biorefinery. pp. 1-2. ISSN 2190-6823. (Published) https://doi.org/10.1007/s13399-020-00909-5 https://doi.org/10.1007/s13399-020-00909-5 |
| spellingShingle | TP Chemical technology Balasundram, Vekes Norazana, Ibrahim Rafiziana, Md. Kasmani Ruzinah, Isha Mohd. Kamaruddin, Abd. Hamid Hasrinah, Hasbullah Catalytic upgrading of biomass-derived pyrolysis vapour over metal-modified HZSM-5 into BTX: a comprehensive review |
| title | Catalytic upgrading of biomass-derived pyrolysis vapour over metal-modified HZSM-5 into BTX: a comprehensive review |
| title_full | Catalytic upgrading of biomass-derived pyrolysis vapour over metal-modified HZSM-5 into BTX: a comprehensive review |
| title_fullStr | Catalytic upgrading of biomass-derived pyrolysis vapour over metal-modified HZSM-5 into BTX: a comprehensive review |
| title_full_unstemmed | Catalytic upgrading of biomass-derived pyrolysis vapour over metal-modified HZSM-5 into BTX: a comprehensive review |
| title_short | Catalytic upgrading of biomass-derived pyrolysis vapour over metal-modified HZSM-5 into BTX: a comprehensive review |
| title_sort | catalytic upgrading of biomass-derived pyrolysis vapour over metal-modified hzsm-5 into btx: a comprehensive review |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/30209/1/Catalytic%20upgrading%20of%20biomass-derived%20pyrolysis%20vapour%20over%20metal.pdf http://umpir.ump.edu.my/id/eprint/30209/ https://doi.org/10.1007/s13399-020-00909-5 https://doi.org/10.1007/s13399-020-00909-5 |
| url_provider | http://umpir.ump.edu.my/ |