Quality restoration of waste polyolefin plastic material through the dissolution-reprecipitation technique

This study examines the restoration of waste plastic polymers based on LDPE, HDPE or PP through dissolution/reprecipitation. Experimental conditions of the recycling process, including type of solvent/non-solvent, original polymer concentration and dissolution temperature were optimized. Results rev...

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Main Authors: Arkan Jasim, Hadi, Najmuldeen, Ghazi Faisal, Ahmed, Iqbal
Format: Article
Language:en
Published: CI and CEQ 2014
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/25432/1/Quality%20restoration%20of%20waste%20polyolefin%20plastic%20material%20through%20the%20dissolution.pdf
http://umpir.ump.edu.my/id/eprint/25432/
https://doi.org/10.2298/CICEQ120526119H
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author Arkan Jasim, Hadi
Najmuldeen, Ghazi Faisal
Ahmed, Iqbal
author_facet Arkan Jasim, Hadi
Najmuldeen, Ghazi Faisal
Ahmed, Iqbal
author_sort Arkan Jasim, Hadi
building UMPSA Library
collection Institutional Repository
content_provider Universiti Malaysia Pahang Al-Sultan Abdullah
content_source UMPSA Institutional Repository
continent Asia
country Malaysia
description This study examines the restoration of waste plastic polymers based on LDPE, HDPE or PP through dissolution/reprecipitation. Experimental conditions of the recycling process, including type of solvent/non-solvent, original polymer concentration and dissolution temperature were optimized. Results revealed that by using the different prepared solvents/non-solvents at various ratios and temperatures, the polymer recovery was always greater than 94%. The FTIR spectra and the thermal properties (melting point and crystallinity) of the polymers before and after recycling were measured using Differential Scanning Calorimetry (DSC). Mechanical properties of the waste polymer before and after recycling were also measured. Besides small occasional deviations, the properties did not change. The tensile strength at maximum load was 7.1, 18.8, and 7.4 MPa for the recycled LDPE, HDPE and PP, respectively and 7.78, 18.54 and 7.86 MPa for the virgin polymer. For the waste, the strength was 6.2, 15.58 and 6.76 MPa.
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spelling my.ump.umpir.254322020-02-11T02:11:31Z http://umpir.ump.edu.my/id/eprint/25432/ Quality restoration of waste polyolefin plastic material through the dissolution-reprecipitation technique Arkan Jasim, Hadi Najmuldeen, Ghazi Faisal Ahmed, Iqbal TP Chemical technology This study examines the restoration of waste plastic polymers based on LDPE, HDPE or PP through dissolution/reprecipitation. Experimental conditions of the recycling process, including type of solvent/non-solvent, original polymer concentration and dissolution temperature were optimized. Results revealed that by using the different prepared solvents/non-solvents at various ratios and temperatures, the polymer recovery was always greater than 94%. The FTIR spectra and the thermal properties (melting point and crystallinity) of the polymers before and after recycling were measured using Differential Scanning Calorimetry (DSC). Mechanical properties of the waste polymer before and after recycling were also measured. Besides small occasional deviations, the properties did not change. The tensile strength at maximum load was 7.1, 18.8, and 7.4 MPa for the recycled LDPE, HDPE and PP, respectively and 7.78, 18.54 and 7.86 MPa for the virgin polymer. For the waste, the strength was 6.2, 15.58 and 6.76 MPa. CI and CEQ 2014 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/25432/1/Quality%20restoration%20of%20waste%20polyolefin%20plastic%20material%20through%20the%20dissolution.pdf Arkan Jasim, Hadi and Najmuldeen, Ghazi Faisal and Ahmed, Iqbal (2014) Quality restoration of waste polyolefin plastic material through the dissolution-reprecipitation technique. Chemical Industry and Chemical Engineering Quarterly, 20 (2). pp. 163-170. ISSN 1451-9372. (Published) https://doi.org/10.2298/CICEQ120526119H https://doi.org/10.2298/CICEQ120526119H
spellingShingle TP Chemical technology
Arkan Jasim, Hadi
Najmuldeen, Ghazi Faisal
Ahmed, Iqbal
Quality restoration of waste polyolefin plastic material through the dissolution-reprecipitation technique
title Quality restoration of waste polyolefin plastic material through the dissolution-reprecipitation technique
title_full Quality restoration of waste polyolefin plastic material through the dissolution-reprecipitation technique
title_fullStr Quality restoration of waste polyolefin plastic material through the dissolution-reprecipitation technique
title_full_unstemmed Quality restoration of waste polyolefin plastic material through the dissolution-reprecipitation technique
title_short Quality restoration of waste polyolefin plastic material through the dissolution-reprecipitation technique
title_sort quality restoration of waste polyolefin plastic material through the dissolution-reprecipitation technique
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/25432/1/Quality%20restoration%20of%20waste%20polyolefin%20plastic%20material%20through%20the%20dissolution.pdf
http://umpir.ump.edu.my/id/eprint/25432/
https://doi.org/10.2298/CICEQ120526119H
https://doi.org/10.2298/CICEQ120526119H
url_provider http://umpir.ump.edu.my/