Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization
Strong anion exchange hypercrosslinked of poly(HEMA-co-EGDMA-co-VBC) (PHEV) and strong anion exchange hypercrosslinked of poly(styrene-co-EGDMA-co-VBC) (PSEV) were prepared via amination reaction with dimethylbutyl amine (DMBA) as the amination agent in dried toluene. The resins were characterized b...
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Bangladesh University of Engineering and Technology
2017
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| Online Access: | http://umpir.ump.edu.my/id/eprint/20601/1/Comparative%20Study%20of%20Strong%20Anion%20Exchange%20Hypercrosslinked%20Poly%28HEMA-co-EGDMA-co-VBC%29%20and%20Strong%20Anion%20Exchange%20Poly%28Styrene-Co-EGDMA-Covbc%29-%20Synthesis%20and%20Characterization.pdf http://umpir.ump.edu.my/id/eprint/20601/ https://www.banglajol.info/index.php/CERB/article/view/33802 |
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| author | Norhayati, Abdullah M. Z., Yahya R., Mahmod |
| author_facet | Norhayati, Abdullah M. Z., Yahya R., Mahmod |
| author_sort | Norhayati, Abdullah |
| building | UMPSA Library |
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| content_provider | Universiti Malaysia Pahang Al-Sultan Abdullah |
| content_source | UMPSA Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | Strong anion exchange hypercrosslinked of poly(HEMA-co-EGDMA-co-VBC) (PHEV) and strong anion exchange hypercrosslinked of poly(styrene-co-EGDMA-co-VBC) (PSEV) were prepared via amination reaction with dimethylbutyl amine (DMBA) as the amination agent in dried toluene. The resins were characterized by SEM, FTIR, BET and elemental analysis. SEM results showed that there was no significant change of the particles shape after amination reaction for both strong anion exchange hypercrosslinked PHEV and strong anion exchange hypercrosslinked PSEV. Specific surface area (SSA) of strong anion exchange hypercrosslinked PHEV increase from 1035 m2/g to 1090 m2/g when amination reaction take place. However, SSA of strong anion exchange hypercrosslinked PHEV decreased from 124 m2/g to 27 m2/g. From FTIR spectra, significant drop occurred at 1265 cm-1 band after amination reaction of strong anion exchange hypercrosslinked PSEV but SSA of strong anion exchange hypercrosslinkedPHEV showed slightly significant drop. Elemental analysis showed that nitrogen content of strong anion exchange hypercrosslinked PHEV significantly increase from 0.10% to 1.46% resulted to high IEC value. Meanwhile, nitrogen content in strong anion exchange hypercrosslinked PSEV only showed small increment in nitrogen content from 0.36% to 0.63% led to low IEC value. |
| format | Article |
| id | my.ump.umpir.20601 |
| institution | Universiti Malaysia Pahang |
| language | en |
| publishDate | 2017 |
| publisher | Bangladesh University of Engineering and Technology |
| record_format | eprints |
| spelling | my.ump.umpir.206012018-02-23T01:10:35Z http://umpir.ump.edu.my/id/eprint/20601/ Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization Norhayati, Abdullah M. Z., Yahya R., Mahmod TP Chemical technology Strong anion exchange hypercrosslinked of poly(HEMA-co-EGDMA-co-VBC) (PHEV) and strong anion exchange hypercrosslinked of poly(styrene-co-EGDMA-co-VBC) (PSEV) were prepared via amination reaction with dimethylbutyl amine (DMBA) as the amination agent in dried toluene. The resins were characterized by SEM, FTIR, BET and elemental analysis. SEM results showed that there was no significant change of the particles shape after amination reaction for both strong anion exchange hypercrosslinked PHEV and strong anion exchange hypercrosslinked PSEV. Specific surface area (SSA) of strong anion exchange hypercrosslinked PHEV increase from 1035 m2/g to 1090 m2/g when amination reaction take place. However, SSA of strong anion exchange hypercrosslinked PHEV decreased from 124 m2/g to 27 m2/g. From FTIR spectra, significant drop occurred at 1265 cm-1 band after amination reaction of strong anion exchange hypercrosslinked PSEV but SSA of strong anion exchange hypercrosslinkedPHEV showed slightly significant drop. Elemental analysis showed that nitrogen content of strong anion exchange hypercrosslinked PHEV significantly increase from 0.10% to 1.46% resulted to high IEC value. Meanwhile, nitrogen content in strong anion exchange hypercrosslinked PSEV only showed small increment in nitrogen content from 0.36% to 0.63% led to low IEC value. Bangladesh University of Engineering and Technology 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/20601/1/Comparative%20Study%20of%20Strong%20Anion%20Exchange%20Hypercrosslinked%20Poly%28HEMA-co-EGDMA-co-VBC%29%20and%20Strong%20Anion%20Exchange%20Poly%28Styrene-Co-EGDMA-Covbc%29-%20Synthesis%20and%20Characterization.pdf Norhayati, Abdullah and M. Z., Yahya and R., Mahmod (2017) Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization. Chemical Engineering Research Bulletin, 19 (Special). pp. 96-101. ISSN 0379-7678 (Print); 2072-9510 (Online). (Published) https://www.banglajol.info/index.php/CERB/article/view/33802 DOI: http://dx.doi.org/10.3329/cerb.v19i0.33802 |
| spellingShingle | TP Chemical technology Norhayati, Abdullah M. Z., Yahya R., Mahmod Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization |
| title | Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization |
| title_full | Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization |
| title_fullStr | Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization |
| title_full_unstemmed | Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization |
| title_short | Comparative Study of Strong Anion Exchange Hypercrosslinked Poly(HEMA-co-EGDMA-co-VBC) and Strong Anion Exchange Poly(Styrene-co-EGDMA-co-VBC): Synthesis and Characterization |
| title_sort | comparative study of strong anion exchange hypercrosslinked poly(hema-co-egdma-co-vbc) and strong anion exchange poly(styrene-co-egdma-co-vbc): synthesis and characterization |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/20601/1/Comparative%20Study%20of%20Strong%20Anion%20Exchange%20Hypercrosslinked%20Poly%28HEMA-co-EGDMA-co-VBC%29%20and%20Strong%20Anion%20Exchange%20Poly%28Styrene-Co-EGDMA-Covbc%29-%20Synthesis%20and%20Characterization.pdf http://umpir.ump.edu.my/id/eprint/20601/ https://www.banglajol.info/index.php/CERB/article/view/33802 |
| url_provider | http://umpir.ump.edu.my/ |