Renewable Syngas Production from Thermal Cracking of Glycerol over Praseodymium-Promoted Ni/Al2O3 Catalyst
In this study, the kinetics of glycerol pyrolysis over a 3wt%Pr-20wt%Ni/77wt%α-Al2O3 catalyst was investigated. The catalyst was synthesized via wet-impregnation method and was characterized using temperature-programmed calcination (TPC), temperature-programmed reduction (TPR), N2-physisorption, FES...
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Elsevier Ltd
2016
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| Online Access: | http://umpir.ump.edu.my/id/eprint/14876/1/pagination_ATE_9328.pdf http://umpir.ump.edu.my/id/eprint/14876/7/fkksa-2016-ck-Renewable%20Syngas%20Production%20from%20Thermal%20Cracking%20of%20Glycerol.pdf http://umpir.ump.edu.my/id/eprint/14876/ http://dx.doi.org/10.1016/j.applthermaleng.2016.10.126 |
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| author | Nor Shahirah, Mohd Nasir Ayodele, Bamidele V. Jolius, Gimbun Lam, Su Shiung Cheng, C. K. |
| author_facet | Nor Shahirah, Mohd Nasir Ayodele, Bamidele V. Jolius, Gimbun Lam, Su Shiung Cheng, C. K. |
| author_sort | Nor Shahirah, Mohd Nasir |
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| content_provider | Universiti Malaysia Pahang Al-Sultan Abdullah |
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| continent | Asia |
| country | Malaysia |
| description | In this study, the kinetics of glycerol pyrolysis over a 3wt%Pr-20wt%Ni/77wt%α-Al2O3 catalyst was investigated. The catalyst was synthesized via wet-impregnation method and was characterized using temperature-programmed calcination (TPC), temperature-programmed reduction (TPR), N2-physisorption, FESEM imaging, X-ray diffraction and CO2-/NH3-temperature-programmed desorption (TPD). The catalytic activity of the as-synthesized 3wt% Pr-Ni/α-Al2O3 catalyst was evaluated in a stainless steel fixed bed reactor at temperatures that ranged from 973 K to 1073 K and a weight-hourly-space-velocity (WHSV) of 4.5×104 ml g-1 h-1 under the atmospheric condition. The main gaseous products from catalytic glycerol pyrolysis were H2, CO, CO2 and CH4 (descending ranking) with the highest H2 formation rate and H2 yield of 0.02593 mol g cat−1 s−1 and 29.04%, respectively. The analysis of the kinetic data obtained from the glycerol pyrolysis showed activation energy of 37.36 kJ mol-1. Based on the mechanistic modeling, it can be deduced that the rate determining step of the glycerol pyrolysis was via a single site associative adsorption with molecular surface reaction as the rate-determining step. |
| format | Article |
| id | my.ump.umpir.14876 |
| institution | Universiti Malaysia Pahang |
| language | en en |
| publishDate | 2016 |
| publisher | Elsevier Ltd |
| record_format | eprints |
| spelling | my.ump.umpir.148762019-08-28T03:23:47Z http://umpir.ump.edu.my/id/eprint/14876/ Renewable Syngas Production from Thermal Cracking of Glycerol over Praseodymium-Promoted Ni/Al2O3 Catalyst Nor Shahirah, Mohd Nasir Ayodele, Bamidele V. Jolius, Gimbun Lam, Su Shiung Cheng, C. K. TP Chemical technology In this study, the kinetics of glycerol pyrolysis over a 3wt%Pr-20wt%Ni/77wt%α-Al2O3 catalyst was investigated. The catalyst was synthesized via wet-impregnation method and was characterized using temperature-programmed calcination (TPC), temperature-programmed reduction (TPR), N2-physisorption, FESEM imaging, X-ray diffraction and CO2-/NH3-temperature-programmed desorption (TPD). The catalytic activity of the as-synthesized 3wt% Pr-Ni/α-Al2O3 catalyst was evaluated in a stainless steel fixed bed reactor at temperatures that ranged from 973 K to 1073 K and a weight-hourly-space-velocity (WHSV) of 4.5×104 ml g-1 h-1 under the atmospheric condition. The main gaseous products from catalytic glycerol pyrolysis were H2, CO, CO2 and CH4 (descending ranking) with the highest H2 formation rate and H2 yield of 0.02593 mol g cat−1 s−1 and 29.04%, respectively. The analysis of the kinetic data obtained from the glycerol pyrolysis showed activation energy of 37.36 kJ mol-1. Based on the mechanistic modeling, it can be deduced that the rate determining step of the glycerol pyrolysis was via a single site associative adsorption with molecular surface reaction as the rate-determining step. Elsevier Ltd 2016-10-21 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/14876/1/pagination_ATE_9328.pdf application/pdf en http://umpir.ump.edu.my/id/eprint/14876/7/fkksa-2016-ck-Renewable%20Syngas%20Production%20from%20Thermal%20Cracking%20of%20Glycerol.pdf Nor Shahirah, Mohd Nasir and Ayodele, Bamidele V. and Jolius, Gimbun and Lam, Su Shiung and Cheng, C. K. (2016) Renewable Syngas Production from Thermal Cracking of Glycerol over Praseodymium-Promoted Ni/Al2O3 Catalyst. Applied Thermal Engineering, 112. pp. 871-880. ISSN 1359-4311. (Published) http://dx.doi.org/10.1016/j.applthermaleng.2016.10.126 doi:10.1016/j.applthermaleng.2016.10.126 |
| spellingShingle | TP Chemical technology Nor Shahirah, Mohd Nasir Ayodele, Bamidele V. Jolius, Gimbun Lam, Su Shiung Cheng, C. K. Renewable Syngas Production from Thermal Cracking of Glycerol over Praseodymium-Promoted Ni/Al2O3 Catalyst |
| title | Renewable Syngas Production from Thermal Cracking of Glycerol over Praseodymium-Promoted Ni/Al2O3 Catalyst |
| title_full | Renewable Syngas Production from Thermal Cracking of Glycerol over Praseodymium-Promoted Ni/Al2O3 Catalyst |
| title_fullStr | Renewable Syngas Production from Thermal Cracking of Glycerol over Praseodymium-Promoted Ni/Al2O3 Catalyst |
| title_full_unstemmed | Renewable Syngas Production from Thermal Cracking of Glycerol over Praseodymium-Promoted Ni/Al2O3 Catalyst |
| title_short | Renewable Syngas Production from Thermal Cracking of Glycerol over Praseodymium-Promoted Ni/Al2O3 Catalyst |
| title_sort | renewable syngas production from thermal cracking of glycerol over praseodymium-promoted ni/al2o3 catalyst |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/14876/1/pagination_ATE_9328.pdf http://umpir.ump.edu.my/id/eprint/14876/7/fkksa-2016-ck-Renewable%20Syngas%20Production%20from%20Thermal%20Cracking%20of%20Glycerol.pdf http://umpir.ump.edu.my/id/eprint/14876/ http://dx.doi.org/10.1016/j.applthermaleng.2016.10.126 |
| url_provider | http://umpir.ump.edu.my/ |