Synthesis, characterization, and thermophysical properties of maghemite (γ-Fe2O3) nanofluids with and without magnetic fields effect / Irwan Nurdin

Synthesis, characterization, and thermophysical properties of maghemite nanofluids have been studied with and without magnetic fields effect. The objectives of study are to synthesize maghemite nanoparticles and their characterization using various methods, to prepare stable maghemite nanofluids, an...

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Main Author: Irwan, Nurdin
Format: Thesis
Published: 2016
Subjects:
Online Access:http://studentsrepo.um.edu.my/6661/4/irwan.pdf
http://studentsrepo.um.edu.my/6661/
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author Irwan, Nurdin
author_facet Irwan, Nurdin
author_sort Irwan, Nurdin
building UM Library
collection Institutional Repository
content_provider Universiti Malaya
content_source UM Student Repository
continent Asia
country Malaysia
description Synthesis, characterization, and thermophysical properties of maghemite nanofluids have been studied with and without magnetic fields effect. The objectives of study are to synthesize maghemite nanoparticles and their characterization using various methods, to prepare stable maghemite nanofluids, and measurement of thermophysical properties of maghemite nanofluids with and without external magnetic fields effect. Maghemite nanoparticles were synthesized by chemical co-precipitation method with different concentrations of nitric acid. Maghemite nanofluids were then prepared and the stability of the nanofluids were characterized by zeta potential and dynamic light scattering at different pH and time of storage. Lastly, measurements of thermal conductivity, viscosity, and electrical conductivity of maghemite nanofluids were taken at various particle volume fraction, temperatures, with and without strengths of magnetic fields. Results show that spherical shape of superparamagnetic maghemite nanoparticles with good thermal and suspensions stability was successfully synthesized within the size range of 9.3 to 14.7 nm. The stability of maghemite nanofluids show that the suspensions remain stable at acidic condition with zeta potential value of 44.6 mV at pH 3.6 and at basic condition with zeta potential -46.2 mV at pH 10.5. The isoelectric point of the maghemite nanoparticles suspensions is obtained at pH 6.7. The maghemite nanofluids remains stable after eight months of storage. The thermal conductivity of maghemite nanofluids linearly increases with increasing of particle volume fraction, temperature, and magnetic fields strengths. The kinematic viscosity of maghemite nanofluids increases with increasing of particle volume fraction and magnetic fields and decrease with increasing of temperature. Electrical conductivity of maghemite nanofluids increases with increasing of particle volume fraction and temperature and no effect with magnetic fields.
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publishDate 2016
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spelling my.um.stud-66612019-09-05T19:51:59Z Synthesis, characterization, and thermophysical properties of maghemite (γ-Fe2O3) nanofluids with and without magnetic fields effect / Irwan Nurdin Irwan, Nurdin TA Engineering (General). Civil engineering (General) Synthesis, characterization, and thermophysical properties of maghemite nanofluids have been studied with and without magnetic fields effect. The objectives of study are to synthesize maghemite nanoparticles and their characterization using various methods, to prepare stable maghemite nanofluids, and measurement of thermophysical properties of maghemite nanofluids with and without external magnetic fields effect. Maghemite nanoparticles were synthesized by chemical co-precipitation method with different concentrations of nitric acid. Maghemite nanofluids were then prepared and the stability of the nanofluids were characterized by zeta potential and dynamic light scattering at different pH and time of storage. Lastly, measurements of thermal conductivity, viscosity, and electrical conductivity of maghemite nanofluids were taken at various particle volume fraction, temperatures, with and without strengths of magnetic fields. Results show that spherical shape of superparamagnetic maghemite nanoparticles with good thermal and suspensions stability was successfully synthesized within the size range of 9.3 to 14.7 nm. The stability of maghemite nanofluids show that the suspensions remain stable at acidic condition with zeta potential value of 44.6 mV at pH 3.6 and at basic condition with zeta potential -46.2 mV at pH 10.5. The isoelectric point of the maghemite nanoparticles suspensions is obtained at pH 6.7. The maghemite nanofluids remains stable after eight months of storage. The thermal conductivity of maghemite nanofluids linearly increases with increasing of particle volume fraction, temperature, and magnetic fields strengths. The kinematic viscosity of maghemite nanofluids increases with increasing of particle volume fraction and magnetic fields and decrease with increasing of temperature. Electrical conductivity of maghemite nanofluids increases with increasing of particle volume fraction and temperature and no effect with magnetic fields. 2016 Thesis NonPeerReviewed application/pdf http://studentsrepo.um.edu.my/6661/4/irwan.pdf Irwan, Nurdin (2016) Synthesis, characterization, and thermophysical properties of maghemite (γ-Fe2O3) nanofluids with and without magnetic fields effect / Irwan Nurdin. PhD thesis, University of Malaya. http://studentsrepo.um.edu.my/6661/
spellingShingle TA Engineering (General). Civil engineering (General)
Irwan, Nurdin
Synthesis, characterization, and thermophysical properties of maghemite (γ-Fe2O3) nanofluids with and without magnetic fields effect / Irwan Nurdin
title Synthesis, characterization, and thermophysical properties of maghemite (γ-Fe2O3) nanofluids with and without magnetic fields effect / Irwan Nurdin
title_full Synthesis, characterization, and thermophysical properties of maghemite (γ-Fe2O3) nanofluids with and without magnetic fields effect / Irwan Nurdin
title_fullStr Synthesis, characterization, and thermophysical properties of maghemite (γ-Fe2O3) nanofluids with and without magnetic fields effect / Irwan Nurdin
title_full_unstemmed Synthesis, characterization, and thermophysical properties of maghemite (γ-Fe2O3) nanofluids with and without magnetic fields effect / Irwan Nurdin
title_short Synthesis, characterization, and thermophysical properties of maghemite (γ-Fe2O3) nanofluids with and without magnetic fields effect / Irwan Nurdin
title_sort synthesis, characterization, and thermophysical properties of maghemite (γ-fe2o3) nanofluids with and without magnetic fields effect / irwan nurdin
topic TA Engineering (General). Civil engineering (General)
url http://studentsrepo.um.edu.my/6661/4/irwan.pdf
http://studentsrepo.um.edu.my/6661/
url_provider http://studentsrepo.um.edu.my/