N-(3-Methylphenyl)quinoxalin-2-amine monohydrate
The quinoxaline system in the title hydrate, C(15)H(13)N(3)center dot H(2)O, is roughly planar, the r.m.s. deviation for the 18 non-H atoms being 0.188 angstrom; this conformation features a short intramolecular C-H center dot center dot center dot N(pyrazine) interaction. In the crystal, the amine...
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International Union of Crystallography
2010
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| Online Access: | http://eprints.um.edu.my/8085/1/Idris-2010-N-%283-Methylphenyl%29qu.pdf http://eprints.um.edu.my/8085/ http://journals.iucr.org/e/issues/2010/09/00/hb5601/hb5601.pdf |
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| author | Ariffin, Azhar Tiekink, E.R.T. Idris, A. Abdullah, Z. Fairuz, Z.A. Ng, S.W. |
| author_facet | Ariffin, Azhar Tiekink, E.R.T. Idris, A. Abdullah, Z. Fairuz, Z.A. Ng, S.W. |
| author_sort | Ariffin, Azhar |
| building | UM Library |
| collection | Institutional Repository |
| content_provider | Universiti Malaya |
| content_source | UM Research Repository |
| continent | Asia |
| country | Malaysia |
| description | The quinoxaline system in the title hydrate, C(15)H(13)N(3)center dot H(2)O, is roughly planar, the r.m.s. deviation for the 18 non-H atoms being 0.188 angstrom; this conformation features a short intramolecular C-H center dot center dot center dot N(pyrazine) interaction. In the crystal, the amine H atom forms an N-H center dot center dot center dot O hydrogen bond to the water molecule, which in turn forms two O-H center dot center dot center dot N hydrogen bonds to the pyrazine N atoms of different organic molecules. These interactions lead to supramolecular arrays in the bc plane that are two molecules thick; additional pi-pi interactions stabilize the layers [ ring centroid-centroid distance = 3.5923 (7) angstrom]. The layers stack along the a-axis direction via C-H center dot center dot center dot pi contacts. |
| format | Article |
| id | my.um.eprints-8085 |
| institution | Universiti Malaya |
| language | en |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | eprints |
| spelling | my.um.eprints-80852019-01-31T01:05:30Z http://eprints.um.edu.my/8085/ N-(3-Methylphenyl)quinoxalin-2-amine monohydrate Ariffin, Azhar Tiekink, E.R.T. Idris, A. Abdullah, Z. Fairuz, Z.A. Ng, S.W. QD Chemistry The quinoxaline system in the title hydrate, C(15)H(13)N(3)center dot H(2)O, is roughly planar, the r.m.s. deviation for the 18 non-H atoms being 0.188 angstrom; this conformation features a short intramolecular C-H center dot center dot center dot N(pyrazine) interaction. In the crystal, the amine H atom forms an N-H center dot center dot center dot O hydrogen bond to the water molecule, which in turn forms two O-H center dot center dot center dot N hydrogen bonds to the pyrazine N atoms of different organic molecules. These interactions lead to supramolecular arrays in the bc plane that are two molecules thick; additional pi-pi interactions stabilize the layers [ ring centroid-centroid distance = 3.5923 (7) angstrom]. The layers stack along the a-axis direction via C-H center dot center dot center dot pi contacts. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/8085/1/Idris-2010-N-%283-Methylphenyl%29qu.pdf Ariffin, Azhar and Tiekink, E.R.T. and Idris, A. and Abdullah, Z. and Fairuz, Z.A. and Ng, S.W. (2010) N-(3-Methylphenyl)quinoxalin-2-amine monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (9). O2276-U60. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810031260 <https://doi.org/10.1107/s1600536810031260>. http://journals.iucr.org/e/issues/2010/09/00/hb5601/hb5601.pdf 10.1107/s1600536810031260 |
| spellingShingle | QD Chemistry Ariffin, Azhar Tiekink, E.R.T. Idris, A. Abdullah, Z. Fairuz, Z.A. Ng, S.W. N-(3-Methylphenyl)quinoxalin-2-amine monohydrate |
| title | N-(3-Methylphenyl)quinoxalin-2-amine monohydrate |
| title_full | N-(3-Methylphenyl)quinoxalin-2-amine monohydrate |
| title_fullStr | N-(3-Methylphenyl)quinoxalin-2-amine monohydrate |
| title_full_unstemmed | N-(3-Methylphenyl)quinoxalin-2-amine monohydrate |
| title_short | N-(3-Methylphenyl)quinoxalin-2-amine monohydrate |
| title_sort | n-(3-methylphenyl)quinoxalin-2-amine monohydrate |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/8085/1/Idris-2010-N-%283-Methylphenyl%29qu.pdf http://eprints.um.edu.my/8085/ http://journals.iucr.org/e/issues/2010/09/00/hb5601/hb5601.pdf |
| url_provider | http://eprints.um.edu.my/ |