Novel high performance hollow fiber ultrafiltration membranes spun from LiBr doped solutions

The objective of this research is to evaluate the performance of the polyethersulfone (PES) hollow fiber ultrafiltration membranes spun from LiBr doped solutions prepared using the newly developed microwave heating technique. In addition the resultant hollow fiber membranes were introduced to a new...

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Main Authors: Idris, A., Ahmed, I., Misran, M.
Format: Article
Published: 2009
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Online Access:http://eprints.um.edu.my/6849/
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author Idris, A.
Ahmed, I.
Misran, M.
author_facet Idris, A.
Ahmed, I.
Misran, M.
author_sort Idris, A.
building UM Library
collection Institutional Repository
content_provider Universiti Malaya
content_source UM Research Repository
continent Asia
country Malaysia
description The objective of this research is to evaluate the performance of the polyethersulfone (PES) hollow fiber ultrafiltration membranes spun from LiBr doped solutions prepared using the newly developed microwave heating technique. In addition the resultant hollow fiber membranes were introduced to a new post-treatment method where the membranes were placed in water and irradiated using the microwave technique. Various concentrations of the additive, LiBr, (1-4 wt.) were added into the PES dope solutions. The dissolution of PES and LiBr in DMF was facilitated by the microwave heating technique. The performance of the membranes was evaluated in terms of pure water permeation and polyethylene glycol separation and its molecular weight cutoff (MWCO) was determined. The results revealed that the microwave post-treatment technique was proven to be effective in producing higher performance membranes. The best performance was obtained at 3 LiBr with MWCO at 90 rejection in the range of 2.83 kDa and high flux range of 222.18 (Lm- 2 h- 1 bar- 1). LiBr interacts in the membrane matrix resulting in the enhancement of the hydrophilic property of the membrane and this is confirmed by the contact angle measurement.
format Article
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institution Universiti Malaya
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spelling my.um.eprints-68492013-09-23T01:24:51Z http://eprints.um.edu.my/6849/ Novel high performance hollow fiber ultrafiltration membranes spun from LiBr doped solutions Idris, A. Ahmed, I. Misran, M. QD Chemistry The objective of this research is to evaluate the performance of the polyethersulfone (PES) hollow fiber ultrafiltration membranes spun from LiBr doped solutions prepared using the newly developed microwave heating technique. In addition the resultant hollow fiber membranes were introduced to a new post-treatment method where the membranes were placed in water and irradiated using the microwave technique. Various concentrations of the additive, LiBr, (1-4 wt.) were added into the PES dope solutions. The dissolution of PES and LiBr in DMF was facilitated by the microwave heating technique. The performance of the membranes was evaluated in terms of pure water permeation and polyethylene glycol separation and its molecular weight cutoff (MWCO) was determined. The results revealed that the microwave post-treatment technique was proven to be effective in producing higher performance membranes. The best performance was obtained at 3 LiBr with MWCO at 90 rejection in the range of 2.83 kDa and high flux range of 222.18 (Lm- 2 h- 1 bar- 1). LiBr interacts in the membrane matrix resulting in the enhancement of the hydrophilic property of the membrane and this is confirmed by the contact angle measurement. 2009 Article PeerReviewed Idris, A. and Ahmed, I. and Misran, M. (2009) Novel high performance hollow fiber ultrafiltration membranes spun from LiBr doped solutions. Desalination, 249 (2). pp. 541-548. ISSN 0011-9164 , DOI https://doi.org/10.1016/j.desal.2008.07.031 <https://doi.org/10.1016/j.desal.2008.07.031>. 10.1016/j.desal.2008.07.031
spellingShingle QD Chemistry
Idris, A.
Ahmed, I.
Misran, M.
Novel high performance hollow fiber ultrafiltration membranes spun from LiBr doped solutions
title Novel high performance hollow fiber ultrafiltration membranes spun from LiBr doped solutions
title_full Novel high performance hollow fiber ultrafiltration membranes spun from LiBr doped solutions
title_fullStr Novel high performance hollow fiber ultrafiltration membranes spun from LiBr doped solutions
title_full_unstemmed Novel high performance hollow fiber ultrafiltration membranes spun from LiBr doped solutions
title_short Novel high performance hollow fiber ultrafiltration membranes spun from LiBr doped solutions
title_sort novel high performance hollow fiber ultrafiltration membranes spun from libr doped solutions
topic QD Chemistry
url http://eprints.um.edu.my/6849/
url_provider http://eprints.um.edu.my/