Micro-structural, thermal, and mechanical properties of injection-molded glass fiber/nanoclay/polypropylene composites

Hybrid composites of PP/NC/GF were prepared by extrusion and injection molding. Molded specimens were analyzed by XRD, SEM, and TEM, together with characterization of thermal and mechanical properties. XRD results revealed that the interaction between NC particles and the PP matrix results in interc...

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Main Authors: Rahman, N.A., Hassan, A., Yahya, R., Lafia-Araga, R.A., Hornsby, P.R.
Format: Article
Published: 2012
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Online Access:http://eprints.um.edu.my/6721/
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author Rahman, N.A.
Hassan, A.
Yahya, R.
Lafia-Araga, R.A.
Hornsby, P.R.
author_facet Rahman, N.A.
Hassan, A.
Yahya, R.
Lafia-Araga, R.A.
Hornsby, P.R.
author_sort Rahman, N.A.
building UM Library
collection Institutional Repository
content_provider Universiti Malaya
content_source UM Research Repository
continent Asia
country Malaysia
description Hybrid composites of PP/NC/GF were prepared by extrusion and injection molding. Molded specimens were analyzed by XRD, SEM, and TEM, together with characterization of thermal and mechanical properties. XRD results revealed that the interaction between NC particles and the PP matrix results in intercalation of the polymer chains, which increases the clay interlayer distance. TEM results revealed NC particle intercalation. TGA results showed that the incorporation of clay into the GF composite improves the thermal stability of the material. The initial thermal decomposition temperatures also shifted to higher values. Incorporation of GF into PP lowers the tensile strength of the binary composite, indicating poor fiber-matrix interfacial adhesion; however, introducing NC increased the strength of the ternary composites. Tensile modulus was enhanced with the incorporation of GF and further increased with an introduction of NC. Flexural strength and flexural modulus are both enhanced with an increase in fiber loading. The addition of clay nanoparticles further improved these properties.
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spelling my.um.eprints-67212013-07-05T02:02:34Z http://eprints.um.edu.my/6721/ Micro-structural, thermal, and mechanical properties of injection-molded glass fiber/nanoclay/polypropylene composites Rahman, N.A. Hassan, A. Yahya, R. Lafia-Araga, R.A. Hornsby, P.R. QD Chemistry Hybrid composites of PP/NC/GF were prepared by extrusion and injection molding. Molded specimens were analyzed by XRD, SEM, and TEM, together with characterization of thermal and mechanical properties. XRD results revealed that the interaction between NC particles and the PP matrix results in intercalation of the polymer chains, which increases the clay interlayer distance. TEM results revealed NC particle intercalation. TGA results showed that the incorporation of clay into the GF composite improves the thermal stability of the material. The initial thermal decomposition temperatures also shifted to higher values. Incorporation of GF into PP lowers the tensile strength of the binary composite, indicating poor fiber-matrix interfacial adhesion; however, introducing NC increased the strength of the ternary composites. Tensile modulus was enhanced with the incorporation of GF and further increased with an introduction of NC. Flexural strength and flexural modulus are both enhanced with an increase in fiber loading. The addition of clay nanoparticles further improved these properties. 2012 Article PeerReviewed Rahman, N.A. and Hassan, A. and Yahya, R. and Lafia-Araga, R.A. and Hornsby, P.R. (2012) Micro-structural, thermal, and mechanical properties of injection-molded glass fiber/nanoclay/polypropylene composites. Journal of Reinforced Plastics and Composites, 31 (4). pp. 269-281. ISSN 07316844, DOI https://doi.org/10.1177/0731684411435727 <https://doi.org/10.1177/0731684411435727>. 10.1177/0731684411435727
spellingShingle QD Chemistry
Rahman, N.A.
Hassan, A.
Yahya, R.
Lafia-Araga, R.A.
Hornsby, P.R.
Micro-structural, thermal, and mechanical properties of injection-molded glass fiber/nanoclay/polypropylene composites
title Micro-structural, thermal, and mechanical properties of injection-molded glass fiber/nanoclay/polypropylene composites
title_full Micro-structural, thermal, and mechanical properties of injection-molded glass fiber/nanoclay/polypropylene composites
title_fullStr Micro-structural, thermal, and mechanical properties of injection-molded glass fiber/nanoclay/polypropylene composites
title_full_unstemmed Micro-structural, thermal, and mechanical properties of injection-molded glass fiber/nanoclay/polypropylene composites
title_short Micro-structural, thermal, and mechanical properties of injection-molded glass fiber/nanoclay/polypropylene composites
title_sort micro-structural, thermal, and mechanical properties of injection-molded glass fiber/nanoclay/polypropylene composites
topic QD Chemistry
url http://eprints.um.edu.my/6721/
url_provider http://eprints.um.edu.my/