N '-5-Chloro-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O-2 diphenyltin(IV)
The Sn-IV atom in the title compound, [Sn(C6H5)(2)(C18H11ClN2O3)], is O,N,O'-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C2SnNO2 trigonal-bipyramidal geometry [C-Sn-C = 125.7 (2)degrees]. The two phenyl rings are oriented at a dihedr...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | en |
| Published: |
International Union of Crystallography
2009
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5368/1/Lee-2009-N_%27-5-Chloro-2-oxido.pdf http://eprints.um.edu.my/5368/ http://journals.iucr.org/e/issues/2009/12/00/xu2687/xu2687.pdf |
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| Summary: | The Sn-IV atom in the title compound, [Sn(C6H5)(2)(C18H11ClN2O3)], is O,N,O'-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C2SnNO2 trigonal-bipyramidal geometry [C-Sn-C = 125.7 (2)degrees]. The two phenyl rings are oriented at a dihedral angle of 55.2 (3)degrees. Intramolecular O-H center dot center dot center dot N hydrogen bonding is present in the crystal structure. |
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