Bis[μ-4-hydr­­oxy-N′-(4-meth­­oxy-2-oxido­benzyl­­idene)benzohydrazidato]bis­­[pyridine­copper(II)]

Bis[μ-4-hydr­­oxy-N′-(4-meth­­oxy-2-oxido­benzyl­­idene)benzohydrazidato]bis­­[pyridine­copper(II)]

In the title compound, [Cu2(C15H12N2O4)2(C6H5N)2], each CuII atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine mol­ecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from the symmetry-related...

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Bibliographic Details
Main Authors: Lair, Nooraziah Mohd, Khaledi, Hamid, Ali, Hapipah Mohd, Puteh, Rustam
Format: Article
Language:en
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
QD Chemistry
Online Access:http://eprints.um.edu.my/5298/1/Lair-2010-Bis_mu-4-hydroxy-N_%27.pdf
http://eprints.um.edu.my/5298/
https://doi.org/10.1107/S1600536810011323
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Summary:In the title compound, [Cu2(C15H12N2O4)2(C6H5N)2], each CuII atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine mol­ecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107 Å). The metal ions are bridged by one O atom from the symmetry-related Schiff base ligands, forming a centrosymmetric dinuclear copper(II) complex. The dimeric complex is linked to another dimer via weaker Cu-O inter­actions and also O-H...N hydrogen bonds.

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