Di-[mu]-thiocyanato-[kappa]2N:S;[kappa]2S:N-bis[bis(2-methyl-1H-benzimidazole-[kappa]N3)(thiocyanato-[kappa]N)cadmium(II)]
The title compound, Cd-2(NCS)(4)(C8H8N2)(4), is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted square-pyramidal geome...
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International Union of Crystallography
2010
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| Online Access: | http://eprints.um.edu.my/5270/1/Shaker-2010-Di-mu-thiocyanato-ka.pdf http://eprints.um.edu.my/5270/ https://doi.org/10.1107/S1600536810042443 |
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| author | Shaker, Shayma A. Khaledi, Hamid Ali, Hapipah Mohd |
| author_facet | Shaker, Shayma A. Khaledi, Hamid Ali, Hapipah Mohd |
| author_sort | Shaker, Shayma A. |
| building | UM Library |
| collection | Institutional Repository |
| content_provider | Universiti Malaya |
| content_source | UM Research Repository |
| continent | Asia |
| country | Malaysia |
| description | The title compound, Cd-2(NCS)(4)(C8H8N2)(4), is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted square-pyramidal geometry around the Cd atom. In the crystal structure, two N-H center dot center dot center dot S hydrogen-bonding interactions occur, resulting in a three-dimensional polymeric structure. The apical 2-methylbenzimidazole ring and its symmetry-related counterpart are arranged in an antiparallel manner with a centroid-centroid separation of 3.6050 (14) angstrom, indicative of a pi-pi interaction. |
| format | Article |
| id | my.um.eprints-5270 |
| institution | Universiti Malaya |
| language | en |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | eprints |
| spelling | my.um.eprints-52702019-11-13T01:08:15Z http://eprints.um.edu.my/5270/ Di-[mu]-thiocyanato-[kappa]2N:S;[kappa]2S:N-bis[bis(2-methyl-1H-benzimidazole-[kappa]N3)(thiocyanato-[kappa]N)cadmium(II)] Shaker, Shayma A. Khaledi, Hamid Ali, Hapipah Mohd Q Science (General) QD Chemistry The title compound, Cd-2(NCS)(4)(C8H8N2)(4), is a centrosymmetric dinuclear cadmium(II) complex in which each two metal ions are linked by a pair of thiocyanate N:S-bridges. Two 2-methylbenzimidazole N-atom donors and one terminal thiocyanate N atom complete a highly distorted square-pyramidal geometry around the Cd atom. In the crystal structure, two N-H center dot center dot center dot S hydrogen-bonding interactions occur, resulting in a three-dimensional polymeric structure. The apical 2-methylbenzimidazole ring and its symmetry-related counterpart are arranged in an antiparallel manner with a centroid-centroid separation of 3.6050 (14) angstrom, indicative of a pi-pi interaction. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5270/1/Shaker-2010-Di-mu-thiocyanato-ka.pdf Shaker, Shayma A. and Khaledi, Hamid and Ali, Hapipah Mohd (2010) Di-[mu]-thiocyanato-[kappa]2N:S;[kappa]2S:N-bis[bis(2-methyl-1H-benzimidazole-[kappa]N3)(thiocyanato-[kappa]N)cadmium(II)]. Acta Crystallographica Section E: Structure Reports Online, E66. M1464. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810042443 <https://doi.org/10.1107/s1600536810042443>. https://doi.org/10.1107/S1600536810042443 doi:10.1107/s1600536810042443 |
| spellingShingle | Q Science (General) QD Chemistry Shaker, Shayma A. Khaledi, Hamid Ali, Hapipah Mohd Di-[mu]-thiocyanato-[kappa]2N:S;[kappa]2S:N-bis[bis(2-methyl-1H-benzimidazole-[kappa]N3)(thiocyanato-[kappa]N)cadmium(II)] |
| title | Di-[mu]-thiocyanato-[kappa]2N:S;[kappa]2S:N-bis[bis(2-methyl-1H-benzimidazole-[kappa]N3)(thiocyanato-[kappa]N)cadmium(II)] |
| title_full | Di-[mu]-thiocyanato-[kappa]2N:S;[kappa]2S:N-bis[bis(2-methyl-1H-benzimidazole-[kappa]N3)(thiocyanato-[kappa]N)cadmium(II)] |
| title_fullStr | Di-[mu]-thiocyanato-[kappa]2N:S;[kappa]2S:N-bis[bis(2-methyl-1H-benzimidazole-[kappa]N3)(thiocyanato-[kappa]N)cadmium(II)] |
| title_full_unstemmed | Di-[mu]-thiocyanato-[kappa]2N:S;[kappa]2S:N-bis[bis(2-methyl-1H-benzimidazole-[kappa]N3)(thiocyanato-[kappa]N)cadmium(II)] |
| title_short | Di-[mu]-thiocyanato-[kappa]2N:S;[kappa]2S:N-bis[bis(2-methyl-1H-benzimidazole-[kappa]N3)(thiocyanato-[kappa]N)cadmium(II)] |
| title_sort | di-[mu]-thiocyanato-[kappa]2n:s;[kappa]2s:n-bis[bis(2-methyl-1h-benzimidazole-[kappa]n3)(thiocyanato-[kappa]n)cadmium(ii)] |
| topic | Q Science (General) QD Chemistry |
| url | http://eprints.um.edu.my/5270/1/Shaker-2010-Di-mu-thiocyanato-ka.pdf http://eprints.um.edu.my/5270/ https://doi.org/10.1107/S1600536810042443 |
| url_provider | http://eprints.um.edu.my/ |