Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc
In the zwitterionic zinc title complex, [ZnCl2(C14H20N2O2)], the Zn-II ion is four-coordinated in a distorted tetrahedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetrahedral coordination en...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | en |
| Published: |
International Union of Crystallography
2011
|
| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5232/1/Hisham-2011-Dichlorido%282-%7B_3-%28mo.pdf http://eprints.um.edu.my/5232/ http://scripts.iucr.org/cgi-bin/paper?S1600536811022021 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1831446934837002240 |
|---|---|
| author | Hisham, N.A.I. Ali, Hapipah Mohd Khaledi, H. |
| author_facet | Hisham, N.A.I. Ali, Hapipah Mohd Khaledi, H. |
| author_sort | Hisham, N.A.I. |
| building | UM Library |
| collection | Institutional Repository |
| content_provider | Universiti Malaya |
| content_source | UM Research Repository |
| continent | Asia |
| country | Malaysia |
| description | In the zwitterionic zinc title complex, [ZnCl2(C14H20N2O2)], the Zn-II ion is four-coordinated in a distorted tetrahedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetrahedral coordination environment. In the crystal, a pair of N-H center dot center dot center dot O hydrogen bonds connect the molecules into a centrosymmetric dimer. C-H center dot center dot center dot O, C-H center dot center dot center dot Cl and C-H center dot center dot center dot pi interactions are also observed. |
| format | Article |
| id | my.um.eprints-5232 |
| institution | Universiti Malaya |
| language | en |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | eprints |
| spelling | my.um.eprints-52322019-01-30T00:55:42Z http://eprints.um.edu.my/5232/ Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc Hisham, N.A.I. Ali, Hapipah Mohd Khaledi, H. QD Chemistry In the zwitterionic zinc title complex, [ZnCl2(C14H20N2O2)], the Zn-II ion is four-coordinated in a distorted tetrahedral geometry. The Schiff base ligand employs its phenolate O and imine N atoms to coordinate the metal atom in a bidentate mode. Two Cl atoms complete the tetrahedral coordination environment. In the crystal, a pair of N-H center dot center dot center dot O hydrogen bonds connect the molecules into a centrosymmetric dimer. C-H center dot center dot center dot O, C-H center dot center dot center dot Cl and C-H center dot center dot center dot pi interactions are also observed. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5232/1/Hisham-2011-Dichlorido%282-%7B_3-%28mo.pdf Hisham, N.A.I. and Ali, Hapipah Mohd and Khaledi, H. (2011) Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc. Acta Crystallographica Section E: Structure Reports Online, 67. M932-U1048. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811022021 <https://doi.org/10.1107/s1600536811022021>. http://scripts.iucr.org/cgi-bin/paper?S1600536811022021 10.1107/s1600536811022021 |
| spellingShingle | QD Chemistry Hisham, N.A.I. Ali, Hapipah Mohd Khaledi, H. Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc |
| title | Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc |
| title_full | Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc |
| title_fullStr | Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc |
| title_full_unstemmed | Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc |
| title_short | Dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc |
| title_sort | dichlorido(2-{ 3-(morpholin-4-ium-4-yl)propyl iminomethyl}phenolate)zinc |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5232/1/Hisham-2011-Dichlorido%282-%7B_3-%28mo.pdf http://eprints.um.edu.my/5232/ http://scripts.iucr.org/cgi-bin/paper?S1600536811022021 |
| url_provider | http://eprints.um.edu.my/ |