Dipotassium disulfanilamidate trihydrate
The asymmetric unit of the title compound, 2K(+)center dot-2C(6)H(7)N(2)O(2)S(-)center dot 3H(2)O, consists of two potassium cations located on mirror planes, one sulfanilamidate anion in a general position and one and a half molecules of water, one of which is also located on a mirror plane. One po...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | en |
| Published: |
International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5230/1/How-2011-Dipotassium_disulfan.pdf http://eprints.um.edu.my/5230/ http://scripts.iucr.org/cgi-bin/paper?S1600536811026791 |
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| Summary: | The asymmetric unit of the title compound, 2K(+)center dot-2C(6)H(7)N(2)O(2)S(-)center dot 3H(2)O, consists of two potassium cations located on mirror planes, one sulfanilamidate anion in a general position and one and a half molecules of water, one of which is also located on a mirror plane. One potassium cation is seven-coordinated by six sulfonyl O atoms and one water molecule, whereas the other is surrounded by six water O atoms and two sulfonyl O atoms. In the crystal structure, the components are connected into polymeric sheets in the bc plane. The two-dimensional structure is consolidated by N-H center dot center dot center dot O, O-H center dot center dot center dot O, O-H center dot center dot center dot N and C-H center dot center dot center dot pi interactions. The layers are further linked into a three-dimensional network via N-H center dot center dot center dot O, N-H center dot center dot center dot N and O-H center dot center dot center dot N hydrogen bonds. |
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