Di-mu-thiocyanato-kappa N-2:S;kappa S-2:N-bis({2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}(thiocyanato-kappa N)cadmium)
In the title complex, [Cd-2(NCS)(4)(C13H19N3O)(2)], the two Cd-II ions are bridged by a pair of thiocyanate N:S-bridging ligands around an inversion center. One terminal thiocyanate N atom and one N,N',N ''-tridentate Schiff base ligand complete a distorted CdN5S octahedral geometry a...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | en |
| Published: |
International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5210/1/Gwaram-2011-Di-mu-thiocyanato-ka.pdf http://eprints.um.edu.my/5210/ http://scripts.iucr.org/cgi-bin/paper?S1600536811002480 |
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| Summary: | In the title complex, [Cd-2(NCS)(4)(C13H19N3O)(2)], the two Cd-II ions are bridged by a pair of thiocyanate N:S-bridging ligands around an inversion center. One terminal thiocyanate N atom and one N,N',N ''-tridentate Schiff base ligand complete a distorted CdN5S octahedral geometry about each Cd-II atom. In the crystal, the Schiff base aromatic rings of adjacent molecules are arranged above each other into infinite chains along the a axis with alternate centroid-centroid separations of 3.5299 (13) and 3.7857 (13) angstrom. |
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