{2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II)
In the title compound, [Cu(NCS)(2)(C13H19N3O)], the Cu-II ion is five-coordinated by the N,N',N ''-tridentate Schiff base and the N atoms of two isothiocyanate ligands in a square-pyramidal geometry. In the crystal, C-H center dot center dot center dot N, C-H center dot center dot cen...
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| Language: | en |
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International Union of Crystallography
2011
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| Online Access: | http://eprints.um.edu.my/5207/1/Gwaram-2011-%7B2-Morpholino-N-_1-%28.pdf http://eprints.um.edu.my/5207/ http://journals.iucr.org/e/issues/2011/01/00/is2639/is2639bdy.html http://doi.org/10.1107/s1600536810050889 |
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| author | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Hisham, N.A.I. |
| author_facet | Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Hisham, N.A.I. |
| author_sort | Gwaram, N.S. |
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| collection | Institutional Repository |
| content_provider | Universiti Malaya |
| content_source | UM Research Repository |
| continent | Asia |
| country | Malaysia |
| description | In the title compound, [Cu(NCS)(2)(C13H19N3O)], the Cu-II ion is five-coordinated by the N,N',N ''-tridentate Schiff base and the N atoms of two isothiocyanate ligands in a square-pyramidal geometry. In the crystal, C-H center dot center dot center dot N, C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions link adjacent molecules into layers parallel to the ac plane. A weak intermolecular pi-pi interaction occurs between the aromatic rings with a centroid-centroid distance of 3.9412 (9) angstrom. |
| format | Article |
| id | my.um.eprints-5207 |
| institution | Universiti Malaya |
| language | en |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | eprints |
| spelling | my.um.eprints-52072019-01-30T01:10:28Z http://eprints.um.edu.my/5207/ {2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II) Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Hisham, N.A.I. QD Chemistry In the title compound, [Cu(NCS)(2)(C13H19N3O)], the Cu-II ion is five-coordinated by the N,N',N ''-tridentate Schiff base and the N atoms of two isothiocyanate ligands in a square-pyramidal geometry. In the crystal, C-H center dot center dot center dot N, C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions link adjacent molecules into layers parallel to the ac plane. A weak intermolecular pi-pi interaction occurs between the aromatic rings with a centroid-centroid distance of 3.9412 (9) angstrom. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5207/1/Gwaram-2011-%7B2-Morpholino-N-_1-%28.pdf Gwaram, N.S. and Ali, Hapipah Mohd and Khaledi, H. and Hisham, N.A.I. (2011) {2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II). Acta Crystallographica Section E: Structure Reports Online, 67. M58-U661. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810050889 <https://doi.org/10.1107/s1600536810050889>. http://journals.iucr.org/e/issues/2011/01/00/is2639/is2639bdy.html http://doi.org/10.1107/s1600536810050889 |
| spellingShingle | QD Chemistry Gwaram, N.S. Ali, Hapipah Mohd Khaledi, H. Hisham, N.A.I. {2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II) |
| title | {2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II) |
| title_full | {2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II) |
| title_fullStr | {2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II) |
| title_full_unstemmed | {2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II) |
| title_short | {2-Morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}bis(thiocyanato-kappa N)copper(II) |
| title_sort | {2-morpholino-n- 1-(2-pyridyl)ethylidene ethanamine-kappa n-3,n ',n ''}bis(thiocyanato-kappa n)copper(ii) |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5207/1/Gwaram-2011-%7B2-Morpholino-N-_1-%28.pdf http://eprints.um.edu.my/5207/ http://journals.iucr.org/e/issues/2011/01/00/is2639/is2639bdy.html http://doi.org/10.1107/s1600536810050889 |
| url_provider | http://eprints.um.edu.my/ |