Dichlorido(4-methoxy-2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}pheno late)cadmium
In the title compound, [CdCl2(C14H21N3O2)], the Schiff base ligand chelates the Cd-II ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent molecules are linked through C-H center dot center dot...
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| Language: | en |
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International Union of Crystallography
2011
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| Online Access: | http://eprints.um.edu.my/5202/1/Salga-2011-Dichlorido%284-methoxy.pdf http://eprints.um.edu.my/5202/ http://journals.iucr.org/e/issues/2011/07/00/issconts.html http://dx.doi.org/10.1107/s1600536811022100 |
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| author | Salga, M.S. Khaledi, H. Ali, Hapipah Mohd |
| author_facet | Salga, M.S. Khaledi, H. Ali, Hapipah Mohd |
| author_sort | Salga, M.S. |
| building | UM Library |
| collection | Institutional Repository |
| content_provider | Universiti Malaya |
| content_source | UM Research Repository |
| continent | Asia |
| country | Malaysia |
| description | In the title compound, [CdCl2(C14H21N3O2)], the Schiff base ligand chelates the Cd-II ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent molecules are linked through C-H center dot center dot center dot pi interactions into infinite chains along the a axis. The molecules are further connected into a three-dimensional network via N-H center dot center dot center dot O, N-H center dot center dot center dot Cl and C-H center dot center dot center dot Cl interactions. The ethylene group is disordered over two sets of sites in a 0.520 (10):0.480 (10) ratio. |
| format | Article |
| id | my.um.eprints-5202 |
| institution | Universiti Malaya |
| language | en |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | eprints |
| spelling | my.um.eprints-52022019-01-30T00:56:01Z http://eprints.um.edu.my/5202/ Dichlorido(4-methoxy-2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}pheno late)cadmium Salga, M.S. Khaledi, H. Ali, Hapipah Mohd QD Chemistry In the title compound, [CdCl2(C14H21N3O2)], the Schiff base ligand chelates the Cd-II ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent molecules are linked through C-H center dot center dot center dot pi interactions into infinite chains along the a axis. The molecules are further connected into a three-dimensional network via N-H center dot center dot center dot O, N-H center dot center dot center dot Cl and C-H center dot center dot center dot Cl interactions. The ethylene group is disordered over two sets of sites in a 0.520 (10):0.480 (10) ratio. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5202/1/Salga-2011-Dichlorido%284-methoxy.pdf Salga, M.S. and Khaledi, H. and Ali, Hapipah Mohd (2011) Dichlorido(4-methoxy-2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}pheno late)cadmium. Acta Crystallographica Section E: Structure Reports Online, E67. m927. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536811022100 <https://doi.org/10.1107/s1600536811022100>. http://journals.iucr.org/e/issues/2011/07/00/issconts.html http://dx.doi.org/10.1107/s1600536811022100 |
| spellingShingle | QD Chemistry Salga, M.S. Khaledi, H. Ali, Hapipah Mohd Dichlorido(4-methoxy-2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}pheno late)cadmium |
| title | Dichlorido(4-methoxy-2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}pheno late)cadmium |
| title_full | Dichlorido(4-methoxy-2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}pheno late)cadmium |
| title_fullStr | Dichlorido(4-methoxy-2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}pheno late)cadmium |
| title_full_unstemmed | Dichlorido(4-methoxy-2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}pheno late)cadmium |
| title_short | Dichlorido(4-methoxy-2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}pheno late)cadmium |
| title_sort | dichlorido(4-methoxy-2-{ 2-(piperazin-4-ium-1-yl)ethyl iminomethyl}pheno late)cadmium |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5202/1/Salga-2011-Dichlorido%284-methoxy.pdf http://eprints.um.edu.my/5202/ http://journals.iucr.org/e/issues/2011/07/00/issconts.html http://dx.doi.org/10.1107/s1600536811022100 |
| url_provider | http://eprints.um.edu.my/ |