Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate]
The ZnII atom in the title polymeric compound, {[Zn(C 8H6NO4)2(H2O) 2]·2H2O} n , lies on a center of inversion and is coordinated by two amine N atoms and two carboxyl-ate O atoms from two 3-amino-5-carb-oxy-benzoate anions along with two water mol-ecules in a distorted octa-hedral geometry. The bri...
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International Union of Crystallography
2012
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| Online Access: | http://eprints.um.edu.my/23091/ https://doi.org/10.1107/S1600536812031789 |
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| _version_ | 1831507493509922816 |
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| author | Zhang, Kou-Lin Qiu, Ting-Ting Ng, Seik Weng |
| author_facet | Zhang, Kou-Lin Qiu, Ting-Ting Ng, Seik Weng |
| author_sort | Zhang, Kou-Lin |
| building | UM Library |
| collection | Institutional Repository |
| content_provider | Universiti Malaya |
| content_source | UM Research Repository |
| continent | Asia |
| country | Malaysia |
| description | The ZnII atom in the title polymeric compound, {[Zn(C 8H6NO4)2(H2O) 2]·2H2O} n , lies on a center of inversion and is coordinated by two amine N atoms and two carboxyl-ate O atoms from two 3-amino-5-carb-oxy-benzoate anions along with two water mol-ecules in a distorted octa-hedral geometry. The bridging nature of the anion generates a layer motif parallel to (100). Hydrogen bonds of the N-H⋯O and O-H⋯O types exist in the structure. One H atom of the coordinated water mol-ecule and one H atom of the solvent water mol-ecule are each disordered over two positions in a 1:1 ratio. |
| format | Article |
| id | my.um.eprints-23091 |
| institution | Universiti Malaya |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | eprints |
| spelling | my.um.eprints-230912019-11-22T06:55:23Z http://eprints.um.edu.my/23091/ Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate] Zhang, Kou-Lin Qiu, Ting-Ting Ng, Seik Weng Q Science (General) QD Chemistry The ZnII atom in the title polymeric compound, {[Zn(C 8H6NO4)2(H2O) 2]·2H2O} n , lies on a center of inversion and is coordinated by two amine N atoms and two carboxyl-ate O atoms from two 3-amino-5-carb-oxy-benzoate anions along with two water mol-ecules in a distorted octa-hedral geometry. The bridging nature of the anion generates a layer motif parallel to (100). Hydrogen bonds of the N-H⋯O and O-H⋯O types exist in the structure. One H atom of the coordinated water mol-ecule and one H atom of the solvent water mol-ecule are each disordered over two positions in a 1:1 ratio. International Union of Crystallography 2012 Article PeerReviewed Zhang, Kou-Lin and Qiu, Ting-Ting and Ng, Seik Weng (2012) Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate]. Acta Crystallographica Section E: Structure Reports Online, 68 (8). m1088-m1088. ISSN 1600-5368, DOI https://doi.org/10.1107/S1600536812031789 <https://doi.org/10.1107/S1600536812031789>. https://doi.org/10.1107/S1600536812031789 doi:10.1107/S1600536812031789 |
| spellingShingle | Q Science (General) QD Chemistry Zhang, Kou-Lin Qiu, Ting-Ting Ng, Seik Weng Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate] |
| title | Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate] |
| title_full | Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate] |
| title_fullStr | Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate] |
| title_full_unstemmed | Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate] |
| title_short | Poly[[bis(μ-3-amino-5-carboxybenzoato-κ2N:O1)diaquazinc] dihydrate] |
| title_sort | poly[[bis(μ-3-amino-5-carboxybenzoato-κ2n:o1)diaquazinc] dihydrate] |
| topic | Q Science (General) QD Chemistry |
| url | http://eprints.um.edu.my/23091/ https://doi.org/10.1107/S1600536812031789 |
| url_provider | http://eprints.um.edu.my/ |