Nitrogen-doped graphene-supported zinc sulfide nanorods as efficient Pt-free for visible-light photocatalytic hydrogen production

Nitrogen-doped graphene-ZnS composite (NG-ZnS) was synthesized by thermal treatment of graphene-ZnS composite (G-ZnS) in NH3 medium. In the second step, the as-synthesized samples were deposited on indium tin oxide glass (ITO) by electrophoretic deposition for photocatalytic hydrogen evolution react...

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Bibliographic Details
Main Authors: Azarang, Majid, Sookhakian, Mehran, Aliahmad, Mousa, Dorraj, Masoumeh, Basirun, Wan Jefrey, Goh, Boon Tong, Alias, Yatimah
Format: Article
Published: Elsevier 2018
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Online Access:http://eprints.um.edu.my/22420/
https://doi.org/10.1016/j.ijhydene.2018.06.082
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Summary:Nitrogen-doped graphene-ZnS composite (NG-ZnS) was synthesized by thermal treatment of graphene-ZnS composite (G-ZnS) in NH3 medium. In the second step, the as-synthesized samples were deposited on indium tin oxide glass (ITO) by electrophoretic deposition for photocatalytic hydrogen evolution reaction. The as-prepared NG-ZnS-modified ITO electrode displayed excellent photocatalytic activity, rapid transient photocurrent response, superior stability and high recyclability compared to the pure ZnS and G-ZnS-modified ITO electrode due to the synergy between the photocatalytic activity of ZnS nanorods and the large surface area and high conductivity of N-graphene.