2-Methyl-3-[(4-methyl-phen-yl)sulfon-yl-oxy]-2-{[(4-methyl-phen-yl)sulfon-yloxy]meth-yl}propyl 4-methyl-benzene-sulfonate
The title mol-ecule, C(26)H(30)O(9)S(3), adopts an extended conformation whereby two approximately parallel benzene rings [dihedral angle = 8.32 (10)°] are orientated in opposite directions along the pseudo-threefold axis through the central quaternary C atom, while a third ring occupies a position...
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| Format: | Article |
| Language: | en |
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International Union of Crystallography
2011
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| Online Access: | http://eprints.um.edu.my/2157/1/2.pdf http://eprints.um.edu.my/2157/ http://www.ncbi.nlm.nih.gov/pubmed/21837205 |
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| author | Al-Mohammed, N.N. Shakir, R.M. Alias, Y. Abdullah, Z. Abd, H.S.N. Tiekink, E.R. |
| author_facet | Al-Mohammed, N.N. Shakir, R.M. Alias, Y. Abdullah, Z. Abd, H.S.N. Tiekink, E.R. |
| author_sort | Al-Mohammed, N.N. |
| building | UM Library |
| collection | Institutional Repository |
| content_provider | Universiti Malaya |
| content_source | UM Research Repository |
| continent | Asia |
| country | Malaysia |
| description | The title mol-ecule, C(26)H(30)O(9)S(3), adopts an extended conformation whereby two approximately parallel benzene rings [dihedral angle = 8.32 (10)°] are orientated in opposite directions along the pseudo-threefold axis through the central quaternary C atom, while a third ring occupies a position mid-way and face-on to these rings [dihedral angles = 82.28 (10) and 78.81 (7)°]. The crystal packing is dominated by C-H⋯O contacts and π-π inter-actions [ring centroid distance = 3.6902 (12) Å]. |
| format | Article |
| id | my.um.eprints-2157 |
| institution | Universiti Malaya |
| language | en |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | eprints |
| spelling | my.um.eprints-21572019-01-30T08:02:41Z http://eprints.um.edu.my/2157/ 2-Methyl-3-[(4-methyl-phen-yl)sulfon-yl-oxy]-2-{[(4-methyl-phen-yl)sulfon-yloxy]meth-yl}propyl 4-methyl-benzene-sulfonate Al-Mohammed, N.N. Shakir, R.M. Alias, Y. Abdullah, Z. Abd, H.S.N. Tiekink, E.R. QD Chemistry The title mol-ecule, C(26)H(30)O(9)S(3), adopts an extended conformation whereby two approximately parallel benzene rings [dihedral angle = 8.32 (10)°] are orientated in opposite directions along the pseudo-threefold axis through the central quaternary C atom, while a third ring occupies a position mid-way and face-on to these rings [dihedral angles = 82.28 (10) and 78.81 (7)°]. The crystal packing is dominated by C-H⋯O contacts and π-π inter-actions [ring centroid distance = 3.6902 (12) Å]. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/2157/1/2.pdf Al-Mohammed, N.N. and Shakir, R.M. and Alias, Y. and Abdullah, Z. and Abd, H.S.N. and Tiekink, E.R. (2011) 2-Methyl-3-[(4-methyl-phen-yl)sulfon-yl-oxy]-2-{[(4-methyl-phen-yl)sulfon-yloxy]meth-yl}propyl 4-methyl-benzene-sulfonate. Acta Crystallographica Section E: Structure Reports Online, 1 (67). ISSN 1600-5368, http://www.ncbi.nlm.nih.gov/pubmed/21837205 |
| spellingShingle | QD Chemistry Al-Mohammed, N.N. Shakir, R.M. Alias, Y. Abdullah, Z. Abd, H.S.N. Tiekink, E.R. 2-Methyl-3-[(4-methyl-phen-yl)sulfon-yl-oxy]-2-{[(4-methyl-phen-yl)sulfon-yloxy]meth-yl}propyl 4-methyl-benzene-sulfonate |
| title | 2-Methyl-3-[(4-methyl-phen-yl)sulfon-yl-oxy]-2-{[(4-methyl-phen-yl)sulfon-yloxy]meth-yl}propyl 4-methyl-benzene-sulfonate |
| title_full | 2-Methyl-3-[(4-methyl-phen-yl)sulfon-yl-oxy]-2-{[(4-methyl-phen-yl)sulfon-yloxy]meth-yl}propyl 4-methyl-benzene-sulfonate |
| title_fullStr | 2-Methyl-3-[(4-methyl-phen-yl)sulfon-yl-oxy]-2-{[(4-methyl-phen-yl)sulfon-yloxy]meth-yl}propyl 4-methyl-benzene-sulfonate |
| title_full_unstemmed | 2-Methyl-3-[(4-methyl-phen-yl)sulfon-yl-oxy]-2-{[(4-methyl-phen-yl)sulfon-yloxy]meth-yl}propyl 4-methyl-benzene-sulfonate |
| title_short | 2-Methyl-3-[(4-methyl-phen-yl)sulfon-yl-oxy]-2-{[(4-methyl-phen-yl)sulfon-yloxy]meth-yl}propyl 4-methyl-benzene-sulfonate |
| title_sort | 2-methyl-3-[(4-methyl-phen-yl)sulfon-yl-oxy]-2-{[(4-methyl-phen-yl)sulfon-yloxy]meth-yl}propyl 4-methyl-benzene-sulfonate |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/2157/1/2.pdf http://eprints.um.edu.my/2157/ http://www.ncbi.nlm.nih.gov/pubmed/21837205 |
| url_provider | http://eprints.um.edu.my/ |