A combined experimental and theoretical investigation on solvent-dependent luminescence behavior of a Cu(I)-MOF
A new Cu(I)-based complex with chemical formulae [Cu7(CN)7(4,4′-bipy)] (1), (4,4′-bipy = 4,4′-bipyridine) has been synthesized and structurally characterized. Single-crystal X-ray analyses reveal that compound 1 exhibits threading network constructed by a 2D sheet and 1D chain. The photoluminescent...
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| Format: | Article |
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Elsevier
2015
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| Online Access: | http://eprints.um.edu.my/19476/ http://dx.doi.org/10.1016/j.inoche.2015.08.025 |
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| author | Wang, J. Gu, C.Y. Li, Q.L. Lu, L. Liu, J.Q. Liu, W.C. Yadav, R. Kumar, A. Ng, S.W. |
| author_facet | Wang, J. Gu, C.Y. Li, Q.L. Lu, L. Liu, J.Q. Liu, W.C. Yadav, R. Kumar, A. Ng, S.W. |
| author_sort | Wang, J. |
| building | UM Library |
| collection | Institutional Repository |
| content_provider | Universiti Malaya |
| content_source | UM Research Repository |
| continent | Asia |
| country | Malaysia |
| description | A new Cu(I)-based complex with chemical formulae [Cu7(CN)7(4,4′-bipy)] (1), (4,4′-bipy = 4,4′-bipyridine) has been synthesized and structurally characterized. Single-crystal X-ray analyses reveal that compound 1 exhibits threading network constructed by a 2D sheet and 1D chain. The photoluminescent property of 1 in different solvents has been investigated and corroborated by theoretical calculations. The obtained results are in good agreement with the results of solvent-dependent luminescence experimental behaviors. An extended analysis of experimental and computational result for 1 indicates that strong metal-solvent bonding interaction plays a dominant role in the sensing of various solvents. |
| format | Article |
| id | my.um.eprints-19476 |
| institution | Universiti Malaya |
| publishDate | 2015 |
| publisher | Elsevier |
| record_format | eprints |
| spelling | my.um.eprints-194762018-09-28T08:26:22Z http://eprints.um.edu.my/19476/ A combined experimental and theoretical investigation on solvent-dependent luminescence behavior of a Cu(I)-MOF Wang, J. Gu, C.Y. Li, Q.L. Lu, L. Liu, J.Q. Liu, W.C. Yadav, R. Kumar, A. Ng, S.W. Q Science (General) QD Chemistry A new Cu(I)-based complex with chemical formulae [Cu7(CN)7(4,4′-bipy)] (1), (4,4′-bipy = 4,4′-bipyridine) has been synthesized and structurally characterized. Single-crystal X-ray analyses reveal that compound 1 exhibits threading network constructed by a 2D sheet and 1D chain. The photoluminescent property of 1 in different solvents has been investigated and corroborated by theoretical calculations. The obtained results are in good agreement with the results of solvent-dependent luminescence experimental behaviors. An extended analysis of experimental and computational result for 1 indicates that strong metal-solvent bonding interaction plays a dominant role in the sensing of various solvents. Elsevier 2015 Article PeerReviewed Wang, J. and Gu, C.Y. and Li, Q.L. and Lu, L. and Liu, J.Q. and Liu, W.C. and Yadav, R. and Kumar, A. and Ng, S.W. (2015) A combined experimental and theoretical investigation on solvent-dependent luminescence behavior of a Cu(I)-MOF. Inorganic Chemistry Communications, 61. pp. 82-84. ISSN 1387-7003, DOI https://doi.org/10.1016/j.inoche.2015.08.025 <https://doi.org/10.1016/j.inoche.2015.08.025>. http://dx.doi.org/10.1016/j.inoche.2015.08.025 doi:10.1016/j.inoche.2015.08.025 |
| spellingShingle | Q Science (General) QD Chemistry Wang, J. Gu, C.Y. Li, Q.L. Lu, L. Liu, J.Q. Liu, W.C. Yadav, R. Kumar, A. Ng, S.W. A combined experimental and theoretical investigation on solvent-dependent luminescence behavior of a Cu(I)-MOF |
| title | A combined experimental and theoretical investigation on solvent-dependent luminescence behavior of a Cu(I)-MOF |
| title_full | A combined experimental and theoretical investigation on solvent-dependent luminescence behavior of a Cu(I)-MOF |
| title_fullStr | A combined experimental and theoretical investigation on solvent-dependent luminescence behavior of a Cu(I)-MOF |
| title_full_unstemmed | A combined experimental and theoretical investigation on solvent-dependent luminescence behavior of a Cu(I)-MOF |
| title_short | A combined experimental and theoretical investigation on solvent-dependent luminescence behavior of a Cu(I)-MOF |
| title_sort | combined experimental and theoretical investigation on solvent-dependent luminescence behavior of a cu(i)-mof |
| topic | Q Science (General) QD Chemistry |
| url | http://eprints.um.edu.my/19476/ http://dx.doi.org/10.1016/j.inoche.2015.08.025 |
| url_provider | http://eprints.um.edu.my/ |