1-Methyl-3,3-bis[(4-methylphenyl)sulfanyl]piperidin-2-one
The piperidone ring in the title compound, C 20H 23NOS 2, has a half-chair distorted to a twisted-boat conformation [Q T = 0.5200 (17) Å]. One of the S-bound benzene rings is almost perpendicular to the least-squares plane through the piperidone ring, whereas the other is not [dihedral angles = 75.2...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2011
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/1832/ https://doi.org/10.1107/S1600536811037111 |
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| Summary: | The piperidone ring in the title compound, C 20H 23NOS 2, has a half-chair distorted to a twisted-boat conformation [Q T = 0.5200 (17) Å]. One of the S-bound benzene rings is almost perpendicular to the least-squares plane through the piperidone ring, whereas the other is not [dihedral angles = 75.28 (5) and 46.41 (5) Å, respectively]. In the crystal, the presence of C-H⋯O and C-H⋯π interactions leads to the formation of supramolecular layers in the ab plane. |
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