catena-Poly[[[dichloridozinc(II)]-mu-1,4-bis(1H-benzimidazol-2-yl- kappa N-3)butane]1,4-bis(1H-benzimidazol-2-yl)butane solvate]
In the crystal structure of the title coordination polymer/co-crystal, {[ZnCl2(C18H18N4)]center dot C18H18N4}(n), the tetrahedrally coordinated Zn-II ions are linked by the N-heterocycle into a linear chain. Another N-heterocycle present is not coordinated to the metal atom but interacts with the ch...
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| Main Authors: | , , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/15280/ |
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| Summary: | In the crystal structure of the title coordination polymer/co-crystal, {[ZnCl2(C18H18N4)]center dot C18H18N4}(n), the tetrahedrally coordinated Zn-II ions are linked by the N-heterocycle into a linear chain. Another N-heterocycle present is not coordinated to the metal atom but interacts with the chain through N-H center dot center dot center dot N and N-H center dot center dot center dot Cl hydrogen bonds. The butyl chain of the uncoordinated ligand is disordered over three positions in a 0.511 (4):0.289 (5):0.200 (5) ratio. |
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