Diaquahexa-mu(2)-dichloroacetato-mu(3)-oxido-tetrahydrofurandiiron(III)m anganese(II)
In the oxido-centered title compound, [Fe2Mn(C2HCl2O2)(6)O(C4H8O)(H2O)(2)], the central O atom is linked to three metal atoms, which are themselves each linked to four dichloroacetate anions, and is in a triangular configuration. Two of the metal atoms are each coordinated by a water molecule, where...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Published: |
International Union of Crystallography
2010
|
| Subjects: | |
| Online Access: | http://eprints.um.edu.my/15277/ |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Summary: | In the oxido-centered title compound, [Fe2Mn(C2HCl2O2)(6)O(C4H8O)(H2O)(2)], the central O atom is linked to three metal atoms, which are themselves each linked to four dichloroacetate anions, and is in a triangular configuration. Two of the metal atoms are each coordinated by a water molecule, whereas the third is coordinated by a tetrahydrofuran molecule. In the crystal, adjacent molecules are linked by O-H center dot center dot center dot O and O-H center dot center dot center dot Cl hydrogen bonds across centers of inversion, generating a hydrogen-bonded chain along the c axis. The Mn-II atoms are disordered with respect to the Fe-III atoms, and the same metal site is occupied by 1/3Mn + 2/3Fe. |
|---|