4-(3,3-Dimethylperhydro-1,3-oxazolo[3,4-a]pyridin-1-yl)-2,8-bis(triflu oromethyl)quinoline

An L-shaped conformation is found in the title molecule, C20H20F6N2O, the C-C-C-C torsion angle linking the two fused-ring systems being -92.80 (19)degrees. The oxazole ring adopts an envelope conformation [the N atom lies 0.579 (2) angstrom out of the plane defined by the remaining atoms], and the...

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Bibliographic Details
Main Authors: Wardell, J.L., Wardell, S.M.S.V., Tiekink, E.R.T.
Format: Article
Published: International Union of Crystallography 2010
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Online Access:http://eprints.um.edu.my/15033/
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Summary:An L-shaped conformation is found in the title molecule, C20H20F6N2O, the C-C-C-C torsion angle linking the two fused-ring systems being -92.80 (19)degrees. The oxazole ring adopts an envelope conformation [the N atom lies 0.579 (2) angstrom out of the plane defined by the remaining atoms], and the piperidine ring has a chair conformation. Supramolecular chains are found in the crystal structure that are sustained by C-H center dot center dot center dot pi and pi-pi [3.6089 (10) angstrom] interactions.