fac-(2-Amidoethyl-kappa C-2(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1)
The asymmetric unit of the title compound, [Sn(C3H6NO)Cl-3(H2O)](2)center dot C12H24O6, comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-,...
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| Main Authors: | , , , , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/15014/ |
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| Summary: | The asymmetric unit of the title compound, [Sn(C3H6NO)Cl-3(H2O)](2)center dot C12H24O6, comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-, O-ligand, and a water molecule. The resulting CCl3O2 donor set defines a distorted octahedral geometry. The tin-bound aqua ligand forms O-H center dot center dot center dot O hydrogen bonds to the centrosymmetric 18-crown-6 molecule, resulting in a tri-molecular aggregate. These assemble into a supramolecular chain along the a axis being connected by N-H center dot center dot center dot O hydrogen bonds. |
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