Bis(2-{[2,8-bis(trifluoromethyl)quinolin-4-yl](hydroxy)methyl}piperi din-1-ium) tetrachloridodiphenylstannate(IV)
In the title salt, (C17H17F6N2O)(2)[Sn(C6H5)(2)Cl-4], the complete anion is generated by crystallograaphic inversion symmetry, giving a trans-SnC2Cl4 octahedral coordination geometry for the metal atom. In the cation, the quinoline residue is almost normal to the other atoms, so that the ion has an...
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| Main Authors: | , , , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/15013/ |
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| Summary: | In the title salt, (C17H17F6N2O)(2)[Sn(C6H5)(2)Cl-4], the complete anion is generated by crystallograaphic inversion symmetry, giving a trans-SnC2Cl4 octahedral coordination geometry for the metal atom. In the cation, the quinoline residue is almost normal to the other atoms, so that the ion has an L-shaped conformation [the C-C-C-C torsion angle linking the fused-ring systems is 100.9 (7)degrees]; the six-membered piperidin-1-ium ring has a chair conformation. An intramolecular N-H center dot center dot center dot O interaction occurs. In the crystal, N-H center dot center dot center dot Cl and O-H center dot center dot center dot Cl hydrogen bonds link the components into a supra-molecular chain propagating along the a axis. C-H center dot center dot center dot Cl interactions are also present. |
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