Encapsulation of unique anionic carboxylic acid/water cluster chains into channels of a three-dimensional cationic framework
The hydrothermal reactions of CuCl with 1,3-bis(4-pyridyl)propane (bpp), 1,3-benzenedicarboxylic acid (1,3-H(2)bdc), and KOH in water afforded {[Cu(8)Cl(4)(bpp)(8)][(1,3-Hbdc)(4)(H(2)O)(9.5)]}(n) (1). Single-crystal X-ray diffraction revealed that 1 has anionic [(1,3-Hbdc)(4)(H(2)O)(9.5)](n)(4n-) wa...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Published: |
Elsevier
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/13109/ |
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| Summary: | The hydrothermal reactions of CuCl with 1,3-bis(4-pyridyl)propane (bpp), 1,3-benzenedicarboxylic acid (1,3-H(2)bdc), and KOH in water afforded {[Cu(8)Cl(4)(bpp)(8)][(1,3-Hbdc)(4)(H(2)O)(9.5)]}(n) (1). Single-crystal X-ray diffraction revealed that 1 has anionic [(1,3-Hbdc)(4)(H(2)O)(9.5)](n)(4n-) water cluster chains that are encapsulated into the 1D channels of a 3-D [Cu(8)Cl(4)(bpp)(8)](n)(4n+) cationic framework. The thermal and luminescent properties of 1 in the solid state were also investigated. (C) 2010 Elsevier BM. All rights reserved. |
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