(N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV)
The Sn atom in the title compound, [Sn(C6H5)(3)(C8H16NS2)], is pentacoordinated by two S atoms, derived from an asymmetrically coordinating dithiocarbamate ligand, and three ipso-C atoms. The coordination geometry is intermediate between square-pyramidal and trigonal-bipyramidal, with a leaning towa...
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| Main Authors: | , , , , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/12409/ |
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| Summary: | The Sn atom in the title compound, [Sn(C6H5)(3)(C8H16NS2)], is pentacoordinated by two S atoms, derived from an asymmetrically coordinating dithiocarbamate ligand, and three ipso-C atoms. The coordination geometry is intermediate between square-pyramidal and trigonal-bipyramidal, with a leaning towards the latter. The presence of close intramolecular C-H center dot center dot center dot S contacts preclude the S atoms from forming significant intermolecular interactions. Rather, molecules are consolidated in the crystal structure by C-H center dot center dot center dot pi interactions. |
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