Preparation, spectroscopic characterization of a new cd(ii) complex containing tridentate nno schiff base derived and x-ray crystallographic structural study of 3,4,5 trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone
A new Cd(II) complex with a tridentate Schiff base derivative which was obtained from condensation of gallic hydrazid with 2-acetylpyridine has been prepared. The structure of the ligand 3,4,5-Trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone (GAPy) was confirmed using the X-ray structure anal...
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Sociedad Chilena de Química
2012
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| Online Access: | http://eprints.um.edu.my/10596/1/PREPARATION%2C_SPECTROSCOPIC_CHARACTERIZATION_OF_A_NEW_Cd%28II%29_COMPLEX_CONTAINING.pdf http://eprints.um.edu.my/10596/ |
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| author | Alhadi, A.A. Shaker, S.A. Gwaram, N.S. Yehye, W.A. Ali, Hapipah Mohd |
| author_facet | Alhadi, A.A. Shaker, S.A. Gwaram, N.S. Yehye, W.A. Ali, Hapipah Mohd |
| author_sort | Alhadi, A.A. |
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| content_provider | Universiti Malaya |
| content_source | UM Research Repository |
| continent | Asia |
| country | Malaysia |
| description | A new Cd(II) complex with a tridentate Schiff base derivative which was obtained from condensation of gallic hydrazid with 2-acetylpyridine has been prepared. The structure of the ligand 3,4,5-Trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone (GAPy) was confirmed using the X-ray structure analysis. The elemental analysis, FTIR, UV-Vis, 1H NMR spectral and Thermal analysis indicates that the Schiff base ligand GAPy is a tridentate ligand which is coordinated with the Cd(II) complex through N,N and O atoms. Thus, the acetate ion is a bidentate ligand that is coordinated with the metal ion through two O atoms. |
| format | Article |
| id | my.um.eprints-10596 |
| institution | Universiti Malaya |
| language | en |
| publishDate | 2012 |
| publisher | Sociedad Chilena de Química |
| record_format | eprints |
| spelling | my.um.eprints-105962019-01-30T01:18:49Z http://eprints.um.edu.my/10596/ Preparation, spectroscopic characterization of a new cd(ii) complex containing tridentate nno schiff base derived and x-ray crystallographic structural study of 3,4,5 trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone Alhadi, A.A. Shaker, S.A. Gwaram, N.S. Yehye, W.A. Ali, Hapipah Mohd QD Chemistry A new Cd(II) complex with a tridentate Schiff base derivative which was obtained from condensation of gallic hydrazid with 2-acetylpyridine has been prepared. The structure of the ligand 3,4,5-Trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone (GAPy) was confirmed using the X-ray structure analysis. The elemental analysis, FTIR, UV-Vis, 1H NMR spectral and Thermal analysis indicates that the Schiff base ligand GAPy is a tridentate ligand which is coordinated with the Cd(II) complex through N,N and O atoms. Thus, the acetate ion is a bidentate ligand that is coordinated with the metal ion through two O atoms. Sociedad Chilena de Química 2012 Article PeerReviewed application/pdf en http://eprints.um.edu.my/10596/1/PREPARATION%2C_SPECTROSCOPIC_CHARACTERIZATION_OF_A_NEW_Cd%28II%29_COMPLEX_CONTAINING.pdf Alhadi, A.A. and Shaker, S.A. and Gwaram, N.S. and Yehye, W.A. and Ali, Hapipah Mohd (2012) Preparation, spectroscopic characterization of a new cd(ii) complex containing tridentate nno schiff base derived and x-ray crystallographic structural study of 3,4,5 trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone. Journal of the Chilean Chemical Society. ISSN 0717-9324, |
| spellingShingle | QD Chemistry Alhadi, A.A. Shaker, S.A. Gwaram, N.S. Yehye, W.A. Ali, Hapipah Mohd Preparation, spectroscopic characterization of a new cd(ii) complex containing tridentate nno schiff base derived and x-ray crystallographic structural study of 3,4,5 trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone |
| title | Preparation, spectroscopic characterization of a new cd(ii) complex containing tridentate nno schiff base derived and x-ray crystallographic structural study of 3,4,5 trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone |
| title_full | Preparation, spectroscopic characterization of a new cd(ii) complex containing tridentate nno schiff base derived and x-ray crystallographic structural study of 3,4,5 trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone |
| title_fullStr | Preparation, spectroscopic characterization of a new cd(ii) complex containing tridentate nno schiff base derived and x-ray crystallographic structural study of 3,4,5 trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone |
| title_full_unstemmed | Preparation, spectroscopic characterization of a new cd(ii) complex containing tridentate nno schiff base derived and x-ray crystallographic structural study of 3,4,5 trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone |
| title_short | Preparation, spectroscopic characterization of a new cd(ii) complex containing tridentate nno schiff base derived and x-ray crystallographic structural study of 3,4,5 trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone |
| title_sort | preparation, spectroscopic characterization of a new cd(ii) complex containing tridentate nno schiff base derived and x-ray crystallographic structural study of 3,4,5 trihydroxybenzoic acid[1-(pyridyl)-ethylidene]hydrazone |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/10596/1/PREPARATION%2C_SPECTROSCOPIC_CHARACTERIZATION_OF_A_NEW_Cd%28II%29_COMPLEX_CONTAINING.pdf http://eprints.um.edu.my/10596/ |
| url_provider | http://eprints.um.edu.my/ |