Bis(4-methoxychalcone 4-ethylthiosemicarbazonato-κ2 N 1,S)zinc(II): Crystal structure and Hirshfeld surface analysis
The title ZnII complex, [Zn(C19H20N3OS)2] {systematic name: bis[(N-ethyl-N0-{(Z)-[(2E)-3-(4-methoxyphenyl)-1-phenylprop-2-en-1-ylidene]amino}carbamimidoyl)sulfanido]zinc(II)}, features a tetrahedrally coordinated ZnII ion within an N2S2 donor set provided by two N,S-chelating thiosemicarbazone anio...
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| Language: | en |
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2018
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| Online Access: | http://eprints.sunway.edu.my/736/1/Tiekink%20Bis%20%284-methoxychalcone%20....%29Acta%20Cryst%202018%20E74%20151.pdf http://eprints.sunway.edu.my/736/ http://dx.doi.org/10.1107/s2056989018000282 |
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| author | Tan, Ming Yueh Crouse, Karen A. Ravoof, Thahira Begum S. A. Jotani, Mukesh M. Tiekink, Edward R. T. * |
| author_facet | Tan, Ming Yueh Crouse, Karen A. Ravoof, Thahira Begum S. A. Jotani, Mukesh M. Tiekink, Edward R. T. * |
| author_sort | Tan, Ming Yueh |
| building | Sunway Campus Library |
| collection | Institutional Repository |
| content_provider | Sunway University |
| content_source | Sunway Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | The title ZnII complex, [Zn(C19H20N3OS)2] {systematic name: bis[(N-ethyl-N0-{(Z)-[(2E)-3-(4-methoxyphenyl)-1-phenylprop-2-en-1-ylidene]amino}carbamimidoyl)sulfanido]zinc(II)}, features a tetrahedrally coordinated ZnII ion within
an N2S2 donor set provided by two N,S-chelating thiosemicarbazone anions. The resulting five-membered Zn,C,N2,S chelate rings adopt different conformations,
i.e. almost planar and an envelope with the Zn atom being the flap atom. The configuration about the imine bond within the chelate ring is Z but those about the exocyclic imine and ethylene bonds are E. In the crystal, supramolecular [100] chains mediated by thioamide-N—H...S(thione) hydrogen bonds and eight-membered thioamide {.....HNCS}2 synthons are observed. A range of interactions, including C—H...O, C—H...., C—H....(chelate ring) and .(methoxybenzene)—.(chelate ring) consolidate the packing. The Hirshfeld surface analysis performed on the title complex also indicates the influence of the interactions involving the chelate rings upon the packing along with the more conventional contacts. |
| format | Article |
| id | my.sunway.eprints.736 |
| institution | Sunway University |
| language | en |
| publishDate | 2018 |
| record_format | eprints |
| spelling | my.sunway.eprints.7362020-10-07T09:18:46Z http://eprints.sunway.edu.my/736/ Bis(4-methoxychalcone 4-ethylthiosemicarbazonato-κ2 N 1,S)zinc(II): Crystal structure and Hirshfeld surface analysis Tan, Ming Yueh Crouse, Karen A. Ravoof, Thahira Begum S. A. Jotani, Mukesh M. Tiekink, Edward R. T. * QD Chemistry The title ZnII complex, [Zn(C19H20N3OS)2] {systematic name: bis[(N-ethyl-N0-{(Z)-[(2E)-3-(4-methoxyphenyl)-1-phenylprop-2-en-1-ylidene]amino}carbamimidoyl)sulfanido]zinc(II)}, features a tetrahedrally coordinated ZnII ion within an N2S2 donor set provided by two N,S-chelating thiosemicarbazone anions. The resulting five-membered Zn,C,N2,S chelate rings adopt different conformations, i.e. almost planar and an envelope with the Zn atom being the flap atom. The configuration about the imine bond within the chelate ring is Z but those about the exocyclic imine and ethylene bonds are E. In the crystal, supramolecular [100] chains mediated by thioamide-N—H...S(thione) hydrogen bonds and eight-membered thioamide {.....HNCS}2 synthons are observed. A range of interactions, including C—H...O, C—H...., C—H....(chelate ring) and .(methoxybenzene)—.(chelate ring) consolidate the packing. The Hirshfeld surface analysis performed on the title complex also indicates the influence of the interactions involving the chelate rings upon the packing along with the more conventional contacts. 2018 Article PeerReviewed text en http://eprints.sunway.edu.my/736/1/Tiekink%20Bis%20%284-methoxychalcone%20....%29Acta%20Cryst%202018%20E74%20151.pdf Tan, Ming Yueh and Crouse, Karen A. and Ravoof, Thahira Begum S. A. and Jotani, Mukesh M. and Tiekink, Edward R. T. * (2018) Bis(4-methoxychalcone 4-ethylthiosemicarbazonato-κ2 N 1,S)zinc(II): Crystal structure and Hirshfeld surface analysis. Acta Crystallographica Section E Crystallographic Communications, 74 (2). pp. 151-157. ISSN 2056-9890 http://dx.doi.org/10.1107/s2056989018000282 doi:10.1107/s2056989018000282 |
| spellingShingle | QD Chemistry Tan, Ming Yueh Crouse, Karen A. Ravoof, Thahira Begum S. A. Jotani, Mukesh M. Tiekink, Edward R. T. * Bis(4-methoxychalcone 4-ethylthiosemicarbazonato-κ2 N 1,S)zinc(II): Crystal structure and Hirshfeld surface analysis |
| title | Bis(4-methoxychalcone 4-ethylthiosemicarbazonato-κ2 N 1,S)zinc(II): Crystal structure and Hirshfeld surface analysis |
| title_full | Bis(4-methoxychalcone 4-ethylthiosemicarbazonato-κ2 N 1,S)zinc(II): Crystal structure and Hirshfeld surface analysis |
| title_fullStr | Bis(4-methoxychalcone 4-ethylthiosemicarbazonato-κ2 N 1,S)zinc(II): Crystal structure and Hirshfeld surface analysis |
| title_full_unstemmed | Bis(4-methoxychalcone 4-ethylthiosemicarbazonato-κ2 N 1,S)zinc(II): Crystal structure and Hirshfeld surface analysis |
| title_short | Bis(4-methoxychalcone 4-ethylthiosemicarbazonato-κ2 N 1,S)zinc(II): Crystal structure and Hirshfeld surface analysis |
| title_sort | bis(4-methoxychalcone 4-ethylthiosemicarbazonato-κ2 n 1,s)zinc(ii): crystal structure and hirshfeld surface analysis |
| topic | QD Chemistry |
| url | http://eprints.sunway.edu.my/736/1/Tiekink%20Bis%20%284-methoxychalcone%20....%29Acta%20Cryst%202018%20E74%20151.pdf http://eprints.sunway.edu.my/736/ http://dx.doi.org/10.1107/s2056989018000282 |
| url_provider | http://eprints.sunway.edu.my/ |