[Dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol
The title compound, [dicyclohexyl(sulfanylidene)-λ5 -phosphanyl]methanol, Cy2P(=S)CH2OH (1), was obtained from the reaction between [Cy2P(CH2OH)2]Cl with one molar equivalent of NaOH and an excess of elemental sulfur (powdered). Characterization was by a single-crystal X-ray structure determinatio...
Saved in:
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | en |
| Published: |
MDPI
2019
|
| Subjects: | |
| Online Access: | http://eprints.sunway.edu.my/1069/1/Tiekink%20Dicyclohexy%20.pdf http://eprints.sunway.edu.my/1069/ http://doi.org/10.3390/M1069 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1831341470733303808 |
|---|---|
| author | Henderson, William Okpareke, Obinna C. Ainnul H. S. Azizan, * Tiekink, Edward R. T. * |
| author_facet | Henderson, William Okpareke, Obinna C. Ainnul H. S. Azizan, * Tiekink, Edward R. T. * |
| author_sort | Henderson, William |
| building | Sunway Campus Library |
| collection | Institutional Repository |
| content_provider | Sunway University |
| content_source | Sunway Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | The title compound, [dicyclohexyl(sulfanylidene)-λ5
-phosphanyl]methanol, Cy2P(=S)CH2OH (1), was obtained from the reaction between [Cy2P(CH2OH)2]Cl with one molar equivalent of NaOH and an excess of elemental sulfur (powdered). Characterization was by a single-crystal X-ray
structure determination as well as IR, and 1D-NMR (1H,13C{1H}, 31P{1H}), and 2D-NMR (DEPT-135 and HSQC) spectroscopy, ESI mass spectrometry, and elemental analysis. X-ray crystallography on Compound 1 shows the phosphorus atom to be tetrahedrally coordinated within a non-symmetric
C3S donor set but with relatively minor distortions from the ideal geometry. In the molecular packing, hydroxyl-O–H· · · S(thione) hydrogen bonds led to supramolecular helical chains along the b-axis direction. |
| format | Article |
| id | my.sunway.eprints.1069 |
| institution | Sunway University |
| language | en |
| publishDate | 2019 |
| publisher | MDPI |
| record_format | eprints |
| spelling | my.sunway.eprints.10692020-10-07T08:35:44Z http://eprints.sunway.edu.my/1069/ [Dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol Henderson, William Okpareke, Obinna C. Ainnul H. S. Azizan, * Tiekink, Edward R. T. * QD Chemistry The title compound, [dicyclohexyl(sulfanylidene)-λ5 -phosphanyl]methanol, Cy2P(=S)CH2OH (1), was obtained from the reaction between [Cy2P(CH2OH)2]Cl with one molar equivalent of NaOH and an excess of elemental sulfur (powdered). Characterization was by a single-crystal X-ray structure determination as well as IR, and 1D-NMR (1H,13C{1H}, 31P{1H}), and 2D-NMR (DEPT-135 and HSQC) spectroscopy, ESI mass spectrometry, and elemental analysis. X-ray crystallography on Compound 1 shows the phosphorus atom to be tetrahedrally coordinated within a non-symmetric C3S donor set but with relatively minor distortions from the ideal geometry. In the molecular packing, hydroxyl-O–H· · · S(thione) hydrogen bonds led to supramolecular helical chains along the b-axis direction. MDPI 2019-07-02 Article PeerReviewed text en cc_by_nc_4 http://eprints.sunway.edu.my/1069/1/Tiekink%20Dicyclohexy%20.pdf Henderson, William and Okpareke, Obinna C. and Ainnul H. S. Azizan, * and Tiekink, Edward R. T. * (2019) [Dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol. Molbank, 2019 (3). M1069. ISSN 1422-8599 http://doi.org/10.3390/M1069 doi:10.3390/M1069 |
| spellingShingle | QD Chemistry Henderson, William Okpareke, Obinna C. Ainnul H. S. Azizan, * Tiekink, Edward R. T. * [Dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol |
| title | [Dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol |
| title_full | [Dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol |
| title_fullStr | [Dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol |
| title_full_unstemmed | [Dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol |
| title_short | [Dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol |
| title_sort | [dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol |
| topic | QD Chemistry |
| url | http://eprints.sunway.edu.my/1069/1/Tiekink%20Dicyclohexy%20.pdf http://eprints.sunway.edu.my/1069/ http://doi.org/10.3390/M1069 |
| url_provider | http://eprints.sunway.edu.my/ |