Chitin nanopaper from mushroom extract: natural composite of nanofibers and glucan from a single biobased source

An isolation method with mild mechanical agitation and no acidic extraction step from a mushroom substrate resulted in chitin nanofibers (ChNFs) with large shares of retained glucans (50−65%). The subsequent chitin nanopapers exhibited exceptionally high tensile strengths of >200 MPa and modul...

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Bibliographic Details
Main Authors: Wan Nawawi, Wan Mohd Fazli, Lee, Koon-Yang, Kontturi, Eero, Murphy, Richard J, Bismarck, Alexander
Format: Article
Language:en
en
en
Published: American Chemical Society 2019
Subjects:
Online Access:http://irep.iium.edu.my/72696/1/72696_Chitin%20Nanopaper%20from%20Mushroom_article.pdf
http://irep.iium.edu.my/72696/2/72696_Chitin%20Nanopaper%20from%20Mushroom_scopus.pdf
http://irep.iium.edu.my/72696/13/72696_Chitin%20Nanopaper%20from%20Mushroom%20Extract%20Natural%20Composite%20of%20Nanofibers%20and%20Glucan%20from%20a%20Single%20Biobased%20Source_wos.pdf
http://irep.iium.edu.my/72696/
https://pubs.acs.org/doi/pdf/10.1021/acssuschemeng.9b00721
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Summary:An isolation method with mild mechanical agitation and no acidic extraction step from a mushroom substrate resulted in chitin nanofibers (ChNFs) with large shares of retained glucans (50−65%). The subsequent chitin nanopapers exhibited exceptionally high tensile strengths of >200 MPa and moduli of ca. 7 GPa, which were largely attributed to the preserved glucans in the mixture, imparting a composite nature to the nanopapers. The isolation method for ChNFs is notably different from the conventional process with crustacean chitin sources that do not incorporate glucans and where an acidic extraction step for the removal of minerals must always be included.