Electrical Characteristics of Aluminum Air Battery Under Open-Circuit And Closed-Circuit Conditions

Aluminium-air battery has great potential as it is capable of achieving high theoretical energy density of 8100 Wh kg-1 , and high theoretical cell voltage of 2.7 V. However, the aluminium anode is vulnerable to self-corrosion and surface passivation issues, causing the practical aluminium-air batte...

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Main Author: Cheah, Zhen Ke
Format: Final Year Project / Dissertation / Thesis
Published: 2020
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Online Access:http://eprints.utar.edu.my/4105/1/1504459_fyp_report_%2D_ZHEN_KE_CHEAH.pdf
http://eprints.utar.edu.my/4105/
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author Cheah, Zhen Ke
author_facet Cheah, Zhen Ke
author_sort Cheah, Zhen Ke
building UTAR Library
collection Institutional Repository
content_provider Universiti Tunku Abdul Rahman
content_source UTAR Institutional Repository
continent Asia
country Malaysia
description Aluminium-air battery has great potential as it is capable of achieving high theoretical energy density of 8100 Wh kg-1 , and high theoretical cell voltage of 2.7 V. However, the aluminium anode is vulnerable to self-corrosion and surface passivation issues, causing the practical aluminium-air battery to yield energy density at only 1300 Wh kg-1 . The practical cell voltage ranges from 1.22 V – 1.46 V for aluminium-air battery in 4M NaOH electrolyte. Therefore, the open-circuit condition such as self-corrosion, surface passivation behaviours, and open-circuit voltage are studied. The closed-circuit condition that includes discharge characteristics is investigated. This research is to study the selfcorrosion and surface passivation behaviours of pure aluminium and alloy 6063 in alkaline electrolyte using SEM-EDX, XRD analysis, and their corresponding open-circuit voltage using potentiostat. Besides that, the effects of graphite felt and graphite powder as catalysts on the discharge characteristic of aluminiumair battery is investigated using potentiostat. The electrolyte for the aluminiumair battery is 4M KOH solution. It is found that alloy 6063 as anode has better electrical characteristics that can achieve 10.3% higher open-circuit voltage, better discharge characteristics on average, and 54 % better capacity as compared to pure aluminium. However, the self-corrosion in alloy 6063 is 60 % faster than pure aluminium based on Tafel plot. The graphite felt is a better catalyst than graphite powder, it has significantly improved the initial discharge voltage by 35 % and 41 %, as well as the final discharge voltage by 65 % and 69 % for pure aluminium and alloy 6063 respectively.
format Final Year Project / Dissertation / Thesis
id my-utar-eprints.4105
institution Universiti Tunku Abdul Rahman
publishDate 2020
record_format eprints
spelling my-utar-eprints.41052021-06-11T17:56:59Z Electrical Characteristics of Aluminum Air Battery Under Open-Circuit And Closed-Circuit Conditions Cheah, Zhen Ke TJ Mechanical engineering and machinery Aluminium-air battery has great potential as it is capable of achieving high theoretical energy density of 8100 Wh kg-1 , and high theoretical cell voltage of 2.7 V. However, the aluminium anode is vulnerable to self-corrosion and surface passivation issues, causing the practical aluminium-air battery to yield energy density at only 1300 Wh kg-1 . The practical cell voltage ranges from 1.22 V – 1.46 V for aluminium-air battery in 4M NaOH electrolyte. Therefore, the open-circuit condition such as self-corrosion, surface passivation behaviours, and open-circuit voltage are studied. The closed-circuit condition that includes discharge characteristics is investigated. This research is to study the selfcorrosion and surface passivation behaviours of pure aluminium and alloy 6063 in alkaline electrolyte using SEM-EDX, XRD analysis, and their corresponding open-circuit voltage using potentiostat. Besides that, the effects of graphite felt and graphite powder as catalysts on the discharge characteristic of aluminiumair battery is investigated using potentiostat. The electrolyte for the aluminiumair battery is 4M KOH solution. It is found that alloy 6063 as anode has better electrical characteristics that can achieve 10.3% higher open-circuit voltage, better discharge characteristics on average, and 54 % better capacity as compared to pure aluminium. However, the self-corrosion in alloy 6063 is 60 % faster than pure aluminium based on Tafel plot. The graphite felt is a better catalyst than graphite powder, it has significantly improved the initial discharge voltage by 35 % and 41 %, as well as the final discharge voltage by 65 % and 69 % for pure aluminium and alloy 6063 respectively. 2020 Final Year Project / Dissertation / Thesis NonPeerReviewed application/pdf http://eprints.utar.edu.my/4105/1/1504459_fyp_report_%2D_ZHEN_KE_CHEAH.pdf Cheah, Zhen Ke (2020) Electrical Characteristics of Aluminum Air Battery Under Open-Circuit And Closed-Circuit Conditions. Final Year Project, UTAR. http://eprints.utar.edu.my/4105/
spellingShingle TJ Mechanical engineering and machinery
Cheah, Zhen Ke
Electrical Characteristics of Aluminum Air Battery Under Open-Circuit And Closed-Circuit Conditions
title Electrical Characteristics of Aluminum Air Battery Under Open-Circuit And Closed-Circuit Conditions
title_full Electrical Characteristics of Aluminum Air Battery Under Open-Circuit And Closed-Circuit Conditions
title_fullStr Electrical Characteristics of Aluminum Air Battery Under Open-Circuit And Closed-Circuit Conditions
title_full_unstemmed Electrical Characteristics of Aluminum Air Battery Under Open-Circuit And Closed-Circuit Conditions
title_short Electrical Characteristics of Aluminum Air Battery Under Open-Circuit And Closed-Circuit Conditions
title_sort electrical characteristics of aluminum air battery under open-circuit and closed-circuit conditions
topic TJ Mechanical engineering and machinery
url http://eprints.utar.edu.my/4105/1/1504459_fyp_report_%2D_ZHEN_KE_CHEAH.pdf
http://eprints.utar.edu.my/4105/
url_provider http://eprints.utar.edu.my