Development of graphitic carbon nitride based assemblies for sunlight driven photocatalysis

This present work focused on the development of binary graphitic carbon nitride (g-C3N4) composite for sunlight driven photocatalysis. In the 1st project, the binary composite was achieved by doping noble metals such as gold (Au), silver (Ag) and palladium (Pd) with g-C3N4 through sunlight photodepo...

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Main Author: Hak, Chen Hong
Format: Final Year Project / Dissertation / Thesis
Published: 2018
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Online Access:http://eprints.utar.edu.my/3572/1/Development_of_graphitic_carbon_nitride_based_assemblies_for_sunlight_driven_photocatalysis.pdf
http://eprints.utar.edu.my/3572/
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author Hak, Chen Hong
author_facet Hak, Chen Hong
author_sort Hak, Chen Hong
building UTAR Library
collection Institutional Repository
content_provider Universiti Tunku Abdul Rahman
content_source UTAR Institutional Repository
continent Asia
country Malaysia
description This present work focused on the development of binary graphitic carbon nitride (g-C3N4) composite for sunlight driven photocatalysis. In the 1st project, the binary composite was achieved by doping noble metals such as gold (Au), silver (Ag) and palladium (Pd) with g-C3N4 through sunlight photodeposition. The deposition of Ag nanoparticles (NPs) (7.5 nm) resulted in the degradation of Bisphenol A (BPA) which was 2.15 fold higher than that of g-C3N4. For 2nd project, carbon dots (CDs) were successfully derived from water hyacinth leaves and the binary composite was achieved by incorporating CDs with g-C3N4 through hydrothermal treatment. The average particle size of CDs was found to be 3.1 nm and a blue-green fluorescence was emitted under the UV light irradiation. Both of 20CDs/g-C3N4 and 40CDs/g-C3N4 achieved the highest degradation efficiency of 2,4-dichlorophenol (2,4-DCP) with 1.7 times higher than that of pure g-C3N4. Both projects successfully improved the properties of g-C3N4 by elongating the lifetime of photogenerated electrons and widening the visible light response. The M/g-C3N4 (M=Au, Ag and Pd) in 1st project fully degraded BPA within 70 min while CDs/g-C3N4 (2nd project) degraded 94% of 2,4-DCP within 120 min. Despite of higher photocatalytic efficiency in the 1st project, CDs/g-C3N4 was recommended for further exploration from the aspect of low production cost and high sustainability.
format Final Year Project / Dissertation / Thesis
id my-utar-eprints.3572
institution Universiti Tunku Abdul Rahman
publishDate 2018
record_format eprints
spelling my-utar-eprints.35722019-09-25T06:26:26Z Development of graphitic carbon nitride based assemblies for sunlight driven photocatalysis Hak, Chen Hong QD Chemistry TA Engineering (General). Civil engineering (General) TK Electrical engineering. Electronics Nuclear engineering This present work focused on the development of binary graphitic carbon nitride (g-C3N4) composite for sunlight driven photocatalysis. In the 1st project, the binary composite was achieved by doping noble metals such as gold (Au), silver (Ag) and palladium (Pd) with g-C3N4 through sunlight photodeposition. The deposition of Ag nanoparticles (NPs) (7.5 nm) resulted in the degradation of Bisphenol A (BPA) which was 2.15 fold higher than that of g-C3N4. For 2nd project, carbon dots (CDs) were successfully derived from water hyacinth leaves and the binary composite was achieved by incorporating CDs with g-C3N4 through hydrothermal treatment. The average particle size of CDs was found to be 3.1 nm and a blue-green fluorescence was emitted under the UV light irradiation. Both of 20CDs/g-C3N4 and 40CDs/g-C3N4 achieved the highest degradation efficiency of 2,4-dichlorophenol (2,4-DCP) with 1.7 times higher than that of pure g-C3N4. Both projects successfully improved the properties of g-C3N4 by elongating the lifetime of photogenerated electrons and widening the visible light response. The M/g-C3N4 (M=Au, Ag and Pd) in 1st project fully degraded BPA within 70 min while CDs/g-C3N4 (2nd project) degraded 94% of 2,4-DCP within 120 min. Despite of higher photocatalytic efficiency in the 1st project, CDs/g-C3N4 was recommended for further exploration from the aspect of low production cost and high sustainability. 2018-10 Final Year Project / Dissertation / Thesis NonPeerReviewed application/pdf http://eprints.utar.edu.my/3572/1/Development_of_graphitic_carbon_nitride_based_assemblies_for_sunlight_driven_photocatalysis.pdf Hak, Chen Hong (2018) Development of graphitic carbon nitride based assemblies for sunlight driven photocatalysis. Master dissertation/thesis, UTAR. http://eprints.utar.edu.my/3572/
spellingShingle QD Chemistry
TA Engineering (General). Civil engineering (General)
TK Electrical engineering. Electronics Nuclear engineering
Hak, Chen Hong
Development of graphitic carbon nitride based assemblies for sunlight driven photocatalysis
title Development of graphitic carbon nitride based assemblies for sunlight driven photocatalysis
title_full Development of graphitic carbon nitride based assemblies for sunlight driven photocatalysis
title_fullStr Development of graphitic carbon nitride based assemblies for sunlight driven photocatalysis
title_full_unstemmed Development of graphitic carbon nitride based assemblies for sunlight driven photocatalysis
title_short Development of graphitic carbon nitride based assemblies for sunlight driven photocatalysis
title_sort development of graphitic carbon nitride based assemblies for sunlight driven photocatalysis
topic QD Chemistry
TA Engineering (General). Civil engineering (General)
TK Electrical engineering. Electronics Nuclear engineering
url http://eprints.utar.edu.my/3572/1/Development_of_graphitic_carbon_nitride_based_assemblies_for_sunlight_driven_photocatalysis.pdf
http://eprints.utar.edu.my/3572/
url_provider http://eprints.utar.edu.my