Structural and luminescence properties of Fe3+ Doped antimony lead borophosphate glass
Structural and luminescence properties of borophosphate glasses with different modifier doped with transition metal ions have been investigated in this study. The glass sample from the series of xPb3O4:0.2Sb2O3:0.3B2O3:(0.5-x)P2O5 and ySb2O3:0.2Pb3O4:(0.5-y)B2O3:0.3P2O5 where 0≤ x ≤0.20 mol% and 0 ≤...
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| Language: | en |
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Universiti Kebangsaan Malaysia
2014
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| Online Access: | http://journalarticle.ukm.my/7182/1/15_Leong_Pau_Ming.pdf http://journalarticle.ukm.my/7182/ http://www.ukm.my/jsm/ |
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| author | Leong, Pau Ming Eeu, Tien Yew Leow, Ting Qiao Pang, Xie Guan Zuhairi Ibrahim, Rosli Hussin, |
| author_facet | Leong, Pau Ming Eeu, Tien Yew Leow, Ting Qiao Pang, Xie Guan Zuhairi Ibrahim, Rosli Hussin, |
| author_sort | Leong, Pau Ming |
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| content_provider | Universiti Kebangsaan Malaysia |
| content_source | UKM Journal Article Repository |
| continent | Asia |
| country | Malaysia |
| description | Structural and luminescence properties of borophosphate glasses with different modifier doped with transition metal ions have been investigated in this study. The glass sample from the series of xPb3O4:0.2Sb2O3:0.3B2O3:(0.5-x)P2O5 and ySb2O3:0.2Pb3O4:(0.5-y)B2O3:0.3P2O5 where 0≤ x ≤0.20 mol% and 0 ≤ y ≤ 0.15mol%, respectively, were doped with 0.01 mol% of Fe2O3 system have been prepared using the melt-quenching technique. The structural properties of samples had been studied using fourier transform infrared (FT-IR) spectroscopy. The FT-IR study showed the network structure of the studied glasses based on the B2O3-P2O5 host with the Sb2O3 and Pb2O3 modifiers. The results of FT-IR showed traces of BO3 and BO4 with the introduction of Sb2O3 and Pb2O3 modifiers. With the increasing content of B2O3 which replacing content of P2O5 in the glass network, the intensity of the borate band decreases and shifted to lower frequency. UV-Vis spectroscopy analysed the transition of Fe3+ from ground state to excited state in the ultraviolet spectral region. The photoluminescence of samples were studied using photoluminescence spectroscopy. The result of photoluminescence spectroscopy showed the effect of photoluminescence enhancement by doping Fe3+ as activator. |
| format | Article |
| id | my-ukm.journal-7182 |
| institution | Universiti Kebangsaan Malaysia |
| language | en |
| publishDate | 2014 |
| publisher | Universiti Kebangsaan Malaysia |
| record_format | eprints |
| spelling | my-ukm.journal-71822016-12-14T06:43:19Z http://journalarticle.ukm.my/7182/ Structural and luminescence properties of Fe3+ Doped antimony lead borophosphate glass Leong, Pau Ming Eeu, Tien Yew Leow, Ting Qiao Pang, Xie Guan Zuhairi Ibrahim, Rosli Hussin, Structural and luminescence properties of borophosphate glasses with different modifier doped with transition metal ions have been investigated in this study. The glass sample from the series of xPb3O4:0.2Sb2O3:0.3B2O3:(0.5-x)P2O5 and ySb2O3:0.2Pb3O4:(0.5-y)B2O3:0.3P2O5 where 0≤ x ≤0.20 mol% and 0 ≤ y ≤ 0.15mol%, respectively, were doped with 0.01 mol% of Fe2O3 system have been prepared using the melt-quenching technique. The structural properties of samples had been studied using fourier transform infrared (FT-IR) spectroscopy. The FT-IR study showed the network structure of the studied glasses based on the B2O3-P2O5 host with the Sb2O3 and Pb2O3 modifiers. The results of FT-IR showed traces of BO3 and BO4 with the introduction of Sb2O3 and Pb2O3 modifiers. With the increasing content of B2O3 which replacing content of P2O5 in the glass network, the intensity of the borate band decreases and shifted to lower frequency. UV-Vis spectroscopy analysed the transition of Fe3+ from ground state to excited state in the ultraviolet spectral region. The photoluminescence of samples were studied using photoluminescence spectroscopy. The result of photoluminescence spectroscopy showed the effect of photoluminescence enhancement by doping Fe3+ as activator. Universiti Kebangsaan Malaysia 2014-06 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/7182/1/15_Leong_Pau_Ming.pdf Leong, Pau Ming and Eeu, Tien Yew and Leow, Ting Qiao and Pang, Xie Guan and Zuhairi Ibrahim, and Rosli Hussin, (2014) Structural and luminescence properties of Fe3+ Doped antimony lead borophosphate glass. Sains Malaysiana, 43 (6). pp. 915-922. ISSN 0126-6039 http://www.ukm.my/jsm/ |
| spellingShingle | Leong, Pau Ming Eeu, Tien Yew Leow, Ting Qiao Pang, Xie Guan Zuhairi Ibrahim, Rosli Hussin, Structural and luminescence properties of Fe3+ Doped antimony lead borophosphate glass |
| title | Structural and luminescence properties of Fe3+ Doped
antimony lead borophosphate glass |
| title_full | Structural and luminescence properties of Fe3+ Doped
antimony lead borophosphate glass |
| title_fullStr | Structural and luminescence properties of Fe3+ Doped
antimony lead borophosphate glass |
| title_full_unstemmed | Structural and luminescence properties of Fe3+ Doped
antimony lead borophosphate glass |
| title_short | Structural and luminescence properties of Fe3+ Doped
antimony lead borophosphate glass |
| title_sort | structural and luminescence properties of fe3+ doped
antimony lead borophosphate glass |
| url | http://journalarticle.ukm.my/7182/1/15_Leong_Pau_Ming.pdf http://journalarticle.ukm.my/7182/ http://www.ukm.my/jsm/ |
| url_provider | http://journalarticle.ukm.my/ |