Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate
Copolymers from different feed compositions of glycidyl methacrylate (GMA) and tetrahydrofurfuryl acrylate (THFA) were synthesized using free radical polymerization in toluene solution at 70±1°C using benzoyl peroxide (BPO) as initiator. The polymers were characterized by 1H NMR,13C NMR and DEPT spe...
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| Format: | Article |
| Language: | en |
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Universiti Kebangsaan Malaysia
2013
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| Online Access: | http://journalarticle.ukm.my/6086/1/12_Ahmad_Danial.pdf http://journalarticle.ukm.my/6086/ http://www.ukm.my/jsm/ |
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| author | Ahmad Danial Azzahari, Rosiyah Yahya, Aziz Hassan, |
| author_facet | Ahmad Danial Azzahari, Rosiyah Yahya, Aziz Hassan, |
| author_sort | Ahmad Danial Azzahari, |
| building | Tun Sri Lanang Library |
| collection | Institutional Repository |
| content_provider | Universiti Kebangsaan Malaysia |
| content_source | UKM Journal Article Repository |
| continent | Asia |
| country | Malaysia |
| description | Copolymers from different feed compositions of glycidyl methacrylate (GMA) and tetrahydrofurfuryl acrylate (THFA) were synthesized using free radical polymerization in toluene solution at 70±1°C using benzoyl peroxide (BPO) as initiator. The polymers were characterized by 1H NMR,13C NMR and DEPT spectroscopic techniques. The copolymer compositions were determined using 1H NMR analysis. Reactivity ratios for GMA and THFA were determined by the Kelen-Tudos, Tidwell-Mortimer and error-in-variables model methods. The results showed that all these copolymerizations were strictly linear systems describable by the Mayo-Lewis equation based on the terminal model and that accurate reactivity ratio data can be obtained. |
| format | Article |
| id | my-ukm.journal-6086 |
| institution | Universiti Kebangsaan Malaysia |
| language | en |
| publishDate | 2013 |
| publisher | Universiti Kebangsaan Malaysia |
| record_format | eprints |
| spelling | my-ukm.journal-60862016-12-14T06:40:20Z http://journalarticle.ukm.my/6086/ Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate Ahmad Danial Azzahari, Rosiyah Yahya, Aziz Hassan, Copolymers from different feed compositions of glycidyl methacrylate (GMA) and tetrahydrofurfuryl acrylate (THFA) were synthesized using free radical polymerization in toluene solution at 70±1°C using benzoyl peroxide (BPO) as initiator. The polymers were characterized by 1H NMR,13C NMR and DEPT spectroscopic techniques. The copolymer compositions were determined using 1H NMR analysis. Reactivity ratios for GMA and THFA were determined by the Kelen-Tudos, Tidwell-Mortimer and error-in-variables model methods. The results showed that all these copolymerizations were strictly linear systems describable by the Mayo-Lewis equation based on the terminal model and that accurate reactivity ratio data can be obtained. Universiti Kebangsaan Malaysia 2013-04 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/6086/1/12_Ahmad_Danial.pdf Ahmad Danial Azzahari, and Rosiyah Yahya, and Aziz Hassan, (2013) Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate. Sains Malaysiana, 42 (4). pp. 509-514. ISSN 0126-6039 http://www.ukm.my/jsm/ |
| spellingShingle | Ahmad Danial Azzahari, Rosiyah Yahya, Aziz Hassan, Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate |
| title | Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate |
| title_full | Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate |
| title_fullStr | Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate |
| title_full_unstemmed | Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate |
| title_short | Reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate |
| title_sort | reactivity ratio determination of newly synthesized copolymers from glycidyl methacrylate and tetrahydrofurfuryl acrylate |
| url | http://journalarticle.ukm.my/6086/1/12_Ahmad_Danial.pdf http://journalarticle.ukm.my/6086/ http://www.ukm.my/jsm/ |
| url_provider | http://journalarticle.ukm.my/ |