Synthesis and Characterisation of Cobalt(II) Complexes of 3-Hydroxyflavone
The syn theses of diaquabis (3-hydroxyflavonato) cobalt(II) and bis(pyridine) bis (3hydroxyflavonato) cobalt(II) are described. Results from infrared spectra clearly show that the 3-hydroxyflavonato anion forms a chelate through the 3-hydroxy 4-keto groups. The electronic spectra of both complexe...
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Universiti Putra Malaysia Press
1995
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my.upm.eprints.38642013-05-27T07:11:51Z http://psasir.upm.edu.my/id/eprint/3864/ Synthesis and Characterisation of Cobalt(II) Complexes of 3-Hydroxyflavone Yang, Farina D. A., Rice The syn theses of diaquabis (3-hydroxyflavonato) cobalt(II) and bis(pyridine) bis (3hydroxyflavonato) cobalt(II) are described. Results from infrared spectra clearly show that the 3-hydroxyflavonato anion forms a chelate through the 3-hydroxy 4-keto groups. The electronic spectra of both complexes indicate that cobalt(II) has an octahedral geometry. Quantitative analyses of the isolated products gave good agreement with calculated values. Magnetic moment measurements show that both compounds are high spin £ cobalt(II) complexes. The powder diffraction pattern of the pyridine adduct gave almost 1:1 correspondence with tTans-bis (pyridine) bis (3-hydroxyflavonato) nickel (II) which has an octahedral geometry. Therefore, it is highly likely that bis(pyridine)bis(3hydroxyflavonato) cobalt(II) is octahedrally co-ordinated with two chelating 3-hydroxyflavonato anions and two pyridine molecules occupying tTans positions. Universiti Putra Malaysia Press 1995 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/3864/1/Synthesis_and_Characterisation_of_Cobalt%28II%29.pdf Yang, Farina and D. A., Rice (1995) Synthesis and Characterisation of Cobalt(II) Complexes of 3-Hydroxyflavone. Pertanika Journal of Science & Technology, 3 (2). pp. 211-219. ISSN 0128-7680 English |
| institution |
Universiti Putra Malaysia |
| building |
UPM Library |
| collection |
Institutional Repository |
| continent |
Asia |
| country |
Malaysia |
| content_provider |
Universiti Putra Malaysia |
| content_source |
UPM Institutional Repository |
| url_provider |
http://psasir.upm.edu.my/ |
| language |
English English |
| description |
The syn theses of diaquabis (3-hydroxyflavonato) cobalt(II) and bis(pyridine) bis (3hydroxyflavonato)
cobalt(II) are described. Results from infrared spectra clearly
show that the 3-hydroxyflavonato anion forms a chelate through the 3-hydroxy
4-keto groups. The electronic spectra of both complexes indicate that cobalt(II)
has an octahedral geometry. Quantitative analyses of the isolated products gave
good agreement with calculated values. Magnetic moment measurements show
that both compounds are high spin £ cobalt(II) complexes. The powder
diffraction pattern of the pyridine adduct gave almost 1:1 correspondence with
tTans-bis (pyridine) bis (3-hydroxyflavonato) nickel (II) which has an octahedral
geometry. Therefore, it is highly likely that bis(pyridine)bis(3hydroxyflavonato)
cobalt(II) is octahedrally co-ordinated with two chelating 3-hydroxyflavonato
anions and two pyridine molecules occupying tTans positions. |
| format |
Article |
| author |
Yang, Farina D. A., Rice |
| spellingShingle |
Yang, Farina D. A., Rice Synthesis and Characterisation of Cobalt(II) Complexes of 3-Hydroxyflavone |
| author_facet |
Yang, Farina D. A., Rice |
| author_sort |
Yang, Farina |
| title |
Synthesis and Characterisation of Cobalt(II)
Complexes of 3-Hydroxyflavone |
| title_short |
Synthesis and Characterisation of Cobalt(II)
Complexes of 3-Hydroxyflavone |
| title_full |
Synthesis and Characterisation of Cobalt(II)
Complexes of 3-Hydroxyflavone |
| title_fullStr |
Synthesis and Characterisation of Cobalt(II)
Complexes of 3-Hydroxyflavone |
| title_full_unstemmed |
Synthesis and Characterisation of Cobalt(II)
Complexes of 3-Hydroxyflavone |
| title_sort |
synthesis and characterisation of cobalt(ii)
complexes of 3-hydroxyflavone |
| publisher |
Universiti Putra Malaysia Press |
| publishDate |
1995 |
| url |
http://psasir.upm.edu.my/id/eprint/3864/1/Synthesis_and_Characterisation_of_Cobalt%28II%29.pdf http://psasir.upm.edu.my/id/eprint/3864/ |
| _version_ |
1643822736264396800 |
| score |
13.250246 |