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Determining the pKa1 and pKa2 Values of 4,4′-Trimethylenedipiperidine (TMDP), a Diprotic Organic Base with Unknown pKa Values

The negative logarithm of the acid dissociation constant values (pK(a1) and pK(a2)) of 4,4 `-trimethylenedipiperidine (TMDP) was determined by a pH metric titration at 298 K. The experimentally determined pK(a) values were compared with the predicted pK(a) values by chem-bioinformatics software like...

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Main Authors: Zaharani, Lia, Khaligh, Nader Ghaffari
格式: Article
出版: Springer 2024
主題:
QD Chemistry
在線閱讀:http://eprints.um.edu.my/45811/
https://doi.org/10.1007/s10953-023-01348-2
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spelling my.um.eprints.458112024-11-12T05:40:57Z http://eprints.um.edu.my/45811/ Determining the pKa1 and pKa2 Values of 4,4′-Trimethylenedipiperidine (TMDP), a Diprotic Organic Base with Unknown pKa Values Zaharani, Lia Khaligh, Nader Ghaffari QD Chemistry The negative logarithm of the acid dissociation constant values (pK(a1) and pK(a2)) of 4,4 `-trimethylenedipiperidine (TMDP) was determined by a pH metric titration at 298 K. The experimentally determined pK(a) values were compared with the predicted pK(a) values by chem-bioinformatics software like ACD/Labs and ChemAxon. This experiment gave an excellent opportunity to deepen engagement with the Henderson-Hasselbalch equation, acid/base dissociation constant (K-a/K-b), and half equivalence point. Springer 2024-06 Article PeerReviewed Zaharani, Lia and Khaligh, Nader Ghaffari (2024) Determining the pKa1 and pKa2 Values of 4,4′-Trimethylenedipiperidine (TMDP), a Diprotic Organic Base with Unknown pKa Values. Journal of Solution Chemistry, 53 (6). pp. 832-840. ISSN 0095-9782, DOI https://doi.org/10.1007/s10953-023-01348-2 <https://doi.org/10.1007/s10953-023-01348-2>. https://doi.org/10.1007/s10953-023-01348-2 10.1007/s10953-023-01348-2
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
spellingShingle QD Chemistry
Zaharani, Lia
Khaligh, Nader Ghaffari
Determining the pKa1 and pKa2 Values of 4,4′-Trimethylenedipiperidine (TMDP), a Diprotic Organic Base with Unknown pKa Values
description The negative logarithm of the acid dissociation constant values (pK(a1) and pK(a2)) of 4,4 `-trimethylenedipiperidine (TMDP) was determined by a pH metric titration at 298 K. The experimentally determined pK(a) values were compared with the predicted pK(a) values by chem-bioinformatics software like ACD/Labs and ChemAxon. This experiment gave an excellent opportunity to deepen engagement with the Henderson-Hasselbalch equation, acid/base dissociation constant (K-a/K-b), and half equivalence point.
format Article
author Zaharani, Lia
Khaligh, Nader Ghaffari
author_facet Zaharani, Lia
Khaligh, Nader Ghaffari
author_sort Zaharani, Lia
title Determining the pKa1 and pKa2 Values of 4,4′-Trimethylenedipiperidine (TMDP), a Diprotic Organic Base with Unknown pKa Values
title_short Determining the pKa1 and pKa2 Values of 4,4′-Trimethylenedipiperidine (TMDP), a Diprotic Organic Base with Unknown pKa Values
title_full Determining the pKa1 and pKa2 Values of 4,4′-Trimethylenedipiperidine (TMDP), a Diprotic Organic Base with Unknown pKa Values
title_fullStr Determining the pKa1 and pKa2 Values of 4,4′-Trimethylenedipiperidine (TMDP), a Diprotic Organic Base with Unknown pKa Values
title_full_unstemmed Determining the pKa1 and pKa2 Values of 4,4′-Trimethylenedipiperidine (TMDP), a Diprotic Organic Base with Unknown pKa Values
title_sort determining the pka1 and pka2 values of 4,4′-trimethylenedipiperidine (tmdp), a diprotic organic base with unknown pka values
publisher Springer
publishDate 2024
url http://eprints.um.edu.my/45811/
https://doi.org/10.1007/s10953-023-01348-2
_version_ 1816130463262048256
score 13.250246

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